(R,R)-BDPP

Name: (R,R)-BDPP
Brand: ChemScene
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CAS No. 96183-46-9
Cat. No. CS-0087736
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 96183-46-9

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General Information

CAS No. 96183-46-9
Cat. No. CS-0087736
Purity ≥98%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₉H₃₀P₂
Molecular Weight 440.50
Synonym(s) (2R,4R)-(+)-2,4-Bis(diphenylphosphino)pentane
SMILES C[C@H](C[C@@H](C)P(C1=CC=CC=C1)C2=CC=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4

Description

(R,R)-BDPP is a chiral bis-diphenylphosphine ligand featuring a rigid, sterically defined backbone that enhances enantioselectivity in transition metal catalysis. This bench-stable, moisture-tolerant ligand integrates seamlessly into asymmetric synthesis workflows, delivering high diastereo- and enantiocontrol in Pd-catalyzed cross-coupling reactions.

Application

(R,R)-BDPP serves as a chiral auxiliary in asymmetric synthesis, enabling stereoselective C–C bond formation through well-established enolate chemistry. Its robust stereocontrol and bench stability facilitate reliable execution of key transformations in complex molecule assembly, particularly in the construction of chiral aliphatic frameworks relevant to pharmaceutical intermediates.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H312-H332-H413
Precautionary Statements : P261-P264-P270-P271-P273-P280-P302+P352-P304+P340-P330-P362+P364-P501

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Computational Chemistry Data

TPSA 0
LogP 6.4193
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 8

Key Words

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(R,R)-BDPP

CAS No. 96183-46-9

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