Methyl morpholine-2-carboxylate hydrochloride

Name: Methyl morpholine-2-carboxylate hydrochloride
Brand: ChemScene
Availability: InStock
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CAS No. 937063-34-8
Cat. No. CS-0036148
Purity≥97%
MDL No.MFCD17167182

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Methyl morpholine-2-carboxylate hydrochloride|CS-0036148

Structure of 937063-34-8

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General Information

CAS No. 937063-34-8
Cat. No. CS-0036148
Purity ≥97%
MDL No. MFCD17167182
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₁₂ClNO₃
Molecular Weight 181.62
Synonym(s) methyl morpholine-2-carboxylate,hydrochloride
SMILES COC(=O)C1CNCCO1.Cl

Description

Methyl morpholine-2-carboxylate hydrochloride features a morpholine ring with a carboxylate ester and protonated nitrogen, enhancing solubility and stability under standard conditions. This bench-stable salt facilitates efficient coupling reactions in synthetic peptide chemistry and serves as a key intermediate in medicinal chemistry workflows.

Application

Methyl morpholine-2-carboxylate hydrochloride serves as a versatile building block in medicinal chemistry, enabling efficient access to bioactive heterocycles. Its stable, bench-ready form facilitates straightforward functionalization and coupling reactions. The morpholine ring provides favorable solubility and metabolic stability, while the ester group supports orthogonal transformations. This compound functions effectively in peptide synthesis and late-stage derivatization workflows.

Synthesis

Route1
- In-stock
  
  500789-41-3
- ~99%
- In-stock
  
  937063-34-8
References
- Ichikawa, Masanori; Ohtsuka, Masami; Ohki, Hitoshi; Haginoya, Noriyasu; Itoh, Masao; Sugita, Kazuyuki; Usui, Hiroyuki; Suzuki, Makoto; Terayama, Koji; Kanda, Akira Bioorganic and Medicinal Chemistry, 2012 , vol. 20, # 9 p. 3072 - 3093
Route2
- In-stock
  
  189321-66-2
- ~%
- In-stock
  
  937063-34-8
References
- Bioorganic and Medicinal Chemistry, , vol. 20, # 9 p. 3072 - 3093

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 47.56
LogP -0.4304
H_Acceptors 4
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Skeleton Aliphatic heterocycle compounds Morpholine compounds

Key Words

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Methyl morpholine-2-carboxylate hydrochloride

CAS No. 937063-34-8

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