[1,1'-Biphenyl]-3,4'-dicarboxylic acid

Name: [1,1'-Biphenyl]-3,4'-dicarboxylic acid
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 92152-01-7
Cat. No. CS-0156957
Purity≥98%
MDL No.MFCD00728324

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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[1,1'-Biphenyl]-3,4'-dicarboxylic acid|CS-0156957

Structure of 92152-01-7

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General Information

CAS No. 92152-01-7
Cat. No. CS-0156957
Purity ≥98%
MDL No. MFCD00728324
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₄H₁₀O₄
Molecular Weight 242.23
Synonym(s) None
SMILES O=C(O)C=1C=CC(=CC1)C2=CC=CC(=C2)C(=O)O

Description

1,1'-Biphenyl]-3,4'-dicarboxylic acid features a rigid biphenyl core with carboxylic acid groups at the 3 and 4' positions, enabling strong coordination in metal-organic frameworks. This arrangement delivers high thermal stability and directional binding, ideal for constructing functional porous materials. The molecule's planar geometry enhances π-stacking interactions, supporting electronic applications in advanced materials.

Application

[1,1'-Biphenyl]-3,4'-dicarboxylic acid serves as a versatile building block for constructing rigid, planar scaffolds in functional materials and pharmaceutical intermediates. Its two carboxylic acid groups enable facile derivatization via amide, ester, or metal coordination chemistry, while the biphenyl core provides excellent thermal stability and defined molecular geometry. The compound exhibits high bench stability and ease of purification, facilitating integration into multi-step synthetic sequences involving coupling reactions, heterocycle formation, or polymer synthesis.

Synthesis

Route1
- 1201925-74-7
- ~92%
- In-stock
  
  92152-01-7
References
- Li, Jian-Rong; Zhou, Hong-Cai Angewandte Chemie - International Edition, 2009 , vol. 48, # 45 p. 8465 - 8468
Route2
- In-stock
  
  25487-66-5
- 74-11-3
- ~96%
- In-stock
  
  92152-01-7
References
- Anderson, Kevin W.; Buchwald, Stephen L. Angewandte Chemie - International Edition, 2005 , vol. 44, # 38 p. 6173 - 6177
Route3
- In-stock
  
  14047-29-1
- In-stock
  
  618-51-9
- ~77%
- In-stock
  
  92152-01-7
References
- Lawson Daku, Kokovi M.; Newton, Roger F.; Pearce, Simon P.; Vile, Julia; Williams, Jonathan M. J. Tetrahedron Letters, 2003 , vol. 44, # 27 p. 5095 - 5098

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 74.6
LogP 2.75
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 3

Other Classifications

Building Blocks Functional Group Carboxylic Acid

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Key Words

[1,1'-Biphenyl]-3,4'-dicarboxylic acid sigma[1,1'-Biphenyl]-3,4'-dicarboxylic acid manufacturer[1,1'-Biphenyl]-3,4'-dicarboxylic acid price[1,1'-Biphenyl]-3,4'-dicarboxylic acid structure[1,1'-Biphenyl]-3,4'-dicarboxylic acid SDSbuy [1,1'-Biphenyl]-3,4'-dicarboxylic acid[1,1'-Biphenyl]-3,4'-dicarboxylic acid supplier[1,1'-Biphenyl]-3,4'-dicarboxylic acid uses[1,1'-Biphenyl]-3,4'-dicarboxylic acid molecular weightprice of [1,1'-Biphenyl]-3,4'-dicarboxylic acid[1,1'-Biphenyl]-3,4'-dicarboxylic acid chemical name formula of [1,1'-Biphenyl]-3,4'-dicarboxylic acid

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[1,1'-Biphenyl]-3,4'-dicarboxylic acid

CAS No. 92152-01-7

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