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CS-W001157 4
Total: USD 88.00

4'-(4-Hydroxyphenyl)-2,2':6',2''-terpyridine

  • CAS No. 89972-79-2

  • Cat. No. CS-0146267
  • Purity≥98%
  • MDL No.MFCD30478583

*For research and further manufacturing use only, not for direct human use.

4'-(4-Hydroxyphenyl)-2,2':6',2''-terpyridine|CS-0146267

Structure of 89972-79-2

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General Information

  • CAS No. 89972-79-2
  • Cat. No. CS-0146267
  • Purity ≥98%
  • MDL No. MFCD30478583
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₁H₁₅N₃O
  • Molecular Weight 325.37
  • Synonym(s) None
  • SMILES OC1=CC=C(C=C1)C2=CC(=NC(=C2)C3=NC=CC=C3)C4=NC=CC=C4

Description

4'-(4-Hydroxyphenyl)-2,2':6',2''-terpyridine features a hydroxylated phenyl group appended to the terpyridine core, enhancing solubility and enabling hydrogen-bonding interactions. This design facilitates coordination with transition metals in catalytic systems and luminescent complexes, offering robust ligand behavior under standard conditions.

Application

4'-(4-Hydroxyphenyl)-2,2':6',2''-terpyridine serves as a versatile ligand scaffold in transition metal catalysis and coordination chemistry. Its terpyridine core enables robust chelation with late-transition metals, while the para-hydroxyphenyl group provides a handle for further functionalization or hydrogen bonding. The molecule exhibits good bench stability and facilitates modular synthesis of luminescent complexes and catalysts used in homogeneous catalysis and materials science.

Synthesis

  • Route1
    • 1-(Pyridin-2-yl)ethanone  Imatinib Impurity|CS-0167014
      1122-62-9
    • p-Hydroxybenzaldehyde Bisoprolol Impurity|CS-0229513
      123-08-0
    • ~43%
    • In-stock
      4'-(4-Hydroxyphenyl)-2,2':6',2''-terpyridine|CS-0146267
      89972-79-2

    References

    • Wang, Jianhua; Hanan, Garry S. Synlett, 2005 , # 8 art. no. S01605ST, p. 1251 - 1254
  • Route2

    References

    • Spahni, Werner; Calzaferri, Gion Helvetica Chimica Acta, 1984 , vol. 67, # 54 p. 450 - 454
  • Route3
    • 1-(Pyridin-2-yl)ethanone  Imatinib Impurity|CS-0167014
      1122-62-9
    • ~%
    • In-stock
      4'-(4-Hydroxyphenyl)-2,2':6',2''-terpyridine|CS-0146267
      89972-79-2

    References

    • Yoo, Dong-Woo; Yoo, Sang-Kun; Kim, Cheal; Lee, Jin-Kyu Journal of the Chemical Society, Dalton Transactions, 2002 , # 21 p. 3931 - 3932

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H312-H332
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362-P501

Quality Control

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Computational Chemistry Data

  • TPSA   58.9
  • LogP   4.5782
  • H_Acceptors   4
  • H_Donors   1
  • Rotatable_Bonds   3

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