4'-Phenyl-2,2':6',2''-terpyridine

Name: 4'-Phenyl-2,2':6',2''-terpyridine
Brand: ChemScene
Availability: InStock
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CAS No. 58345-97-4
Cat. No. CS-0110561
Purity≥97%
MDL No.MFCD03838803

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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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4'-Phenyl-2,2':6',2''-terpyridine|CS-0110561

Structure of 58345-97-4

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General Information

CAS No. 58345-97-4
Cat. No. CS-0110561
Purity ≥97%
MDL No. MFCD03838803
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₁H₁₅N₃
Molecular Weight 309.37
Synonym(s) None
SMILES N=1C=CC=CC1C2=NC(=CC(=C2)C3=CC=CC=C3)C4=NC=CC=C4

Description

4'-Phenyl-2,2':6',2''-terpyridine features a rigid, planar tridentate architecture that facilitates strong coordination with transition metals. This extended π-system enhances electronic communication across metal-ligand interfaces, making it ideal for constructing luminescent complexes and catalytic frameworks in coordination chemistry.

Application

4'-Phenyl-2,2':6',2''-terpyridine serves as a versatile ligand scaffold in transition metal coordination chemistry, enabling robust complexation with late-transition metals due to its extended π-conjugated framework and three nitrogen donor sites. Its phenyl substitution enhances solubility and modulates redox properties, while maintaining excellent bench stability and ease of purification—making it well-suited for catalytic applications and materials synthesis.

Synthesis

Route1
- 1122-62-9
- 100-52-7
- ~82%
- In-stock
  
  58345-97-4
References
- Tu, Shujiang; Jia, Runhong; Jiang, Bo; Zhang, Junyong; Zhang, Yan; Yao, Changsheng; Ji, Shunjun Tetrahedron, 2007 , vol. 63, # 2 p. 381 - 388
Route2
- 133762-11-5
- ~%
- In-stock
  
  58345-97-4
References
- Frank; Riener Journal of the American Chemical Society, 1950 , vol. 72, p. 4182
Route3
- 1122-62-9
- ~%
- In-stock
  
  58345-97-4
References
- Winter, Andreas; Van Den Berg, Antje M. J.; Hoogenboom, Richard; Kickelbick, Guido; Schubert, Ulrich S. Synthesis, 2006 , # 17 p. 2873 - 2878

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 38.67
LogP 4.8726
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 3

Other Classifications

Material Science Material Composite Block Optoelectronic Material Intermediate

Material Science Material Building Blocks Ligands for Functional Metal Complexes Bipyridine Ligands, Terpyridine Ligands

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Key Words

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4'-Phenyl-2,2':6',2''-terpyridine

CAS No. 58345-97-4

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