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CS-W001157 4
Total: USD 88.00

4'-(4-Chlorophenyl)-2,2':6',2''-terpyridine

  • CAS No. 89972-75-8

  • Cat. No. CS-W018454
  • Purity≥95%
  • MDL No.MFCD06796985

*For research and further manufacturing use only, not for direct human use.

4'-(4-Chlorophenyl)-2,2':6',2''-terpyridine|CS-W018454

Structure of 89972-75-8

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General Information

  • CAS No. 89972-75-8
  • Cat. No. CS-W018454
  • Purity ≥95%
  • MDL No. MFCD06796985
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₁H₁₄ClN₃
  • Molecular Weight 343.81
  • Synonym(s) None
  • SMILES ClC1=CC=C(C=C1)C2=CC(=NC(=C2)C3=NC=CC=C3)C4=NC=CC=C4

Application

4'-(4-Chlorophenyl)-2,2':6',2''-terpyridine serves as a versatile ligand scaffold in transition metal catalysis and coordination chemistry. Its extended π-system and orthogonal functionalization enable robust complexation with late transition metals, facilitating applications in homogeneous catalysis and luminescent materials. The chlorophenyl group enhances electronic tuning and provides a handle for further derivatization via cross-coupling reactions. Bench-stable and readily purified by recrystallization, it functions effectively in standard synthetic workflows requiring modular ligand design.

Synthesis

  • Route1

    References

    • Tu, Shujiang; Jia, Runhong; Jiang, Bo; Zhang, Junyong; Zhang, Yan; Yao, Changsheng; Ji, Shunjun Tetrahedron, 2007 , vol. 63, # 2 p. 381 - 388
  • Route2
    • In-stock
      1-(2-Oxo-2-(pyridin-2-yl)ethyl)pyridin-1-ium iodide|CS-0450337
      26482-00-8
    • null|null
      16231-98-4
    • ~82%
    • In-stock
      4'-(4-Chlorophenyl)-2,2':6',2''-terpyridine|CS-W018454
      89972-75-8

    References

    • Mutai, Toshiki; Cheon, Jin-Dong; Arita, Shinpei; Araki, Koji Journal of the Chemical Society. Perkin Transactions 2, 2001 , # 7 p. 1045 - 1050
  • Route3
    • 1-(Pyridin-2-yl)ethanone  Imatinib Impurity|CS-0167014
      1122-62-9
    • ~%
    • In-stock
      4'-(4-Chlorophenyl)-2,2':6',2''-terpyridine|CS-W018454
      89972-75-8

    References

    • Winter, Andreas; Van Den Berg, Antje M. J.; Hoogenboom, Richard; Kickelbick, Guido; Schubert, Ulrich S. Synthesis, 2006 , # 17 p. 2873 - 2878

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS06
Signal Word : Danger
UN#: 2811
Class : 6.1
Packing Group : Ⅲ
Hazard Statements : H301-H413
Precautionary Statements : P264-P270-P273-P330-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   38.67
  • LogP   5.526
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   3

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