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CS-W001157 4
Total: USD 88.00

2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl fluoride

  • CAS No. 89025-46-7

  • Cat. No. CS-0226064
  • Molecule weight542.64
  • Purity≥97%
  • MDL No.MFCD03701104

*For research and further manufacturing use only, not for direct human use.

2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl fluoride|CS-0226064

Structure of 89025-46-7

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General Information

  • CAS No. 89025-46-7
  • Cat. No. CS-0226064
  • Purity ≥97%
  • MDL No. MFCD03701104
  • Storage Sealed in dry,2-8℃
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₄H₃₅FO₅
  • Molecular Weight 542.64
  • Synonym(s) 2,3,4,6-Tetra-O-benzyl-alpha-D-glucopyranosyl fluoride
  • SMILES F[C@H]([C@@H]1OCC2=CC=CC=C2)O[C@H](COCC3=CC=CC=C3)[C@@H](OCC4=CC=CC=C4)[C@@H]1OCC5=CC=CC=C5

Synthesis

  • Route1
    • (2r,3r,4s,5r,6s)-3,4,5-Tris(benzyloxy)-2-((benzyloxy)methyl)-6-(phenylthio)tetrahydro-2h-pyran|CS-0664244
      38184-10-0
    • ~79%
    • 2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl fluoride|CS-0226064
      89025-46-7

    References

    • Suzuki, Shinkiti; Matsumoto, Kouichi; Kawamura, Kohsuke; Suga, Seiji; Yoshida, Jun-Ichi Organic Letters, 2004 , vol. 6, # 21 p. 3755 - 3758
  • Route2
    • null|null
      113548-09-7
    • ~83%
    • 2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl fluoride|CS-0226064
      89025-46-7

    References

    • Fraser-Reid, Bert; Lopez, J. Cristobal; Bernal-Albert, Paloma; Gomez, Ana M.; Uriel, Clara; Ventura, Juan Canadian Journal of Chemistry, 2013 , vol. 91, # 1 p. 51 - 65
  • Route3
    • (2S,3R,4S,5S,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-ol|CS-0504838
      4291-69-4
    • ~82%
    • 2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl fluoride|CS-0226064
      89025-46-7

    References

    • Umemoto, Teruo; Singh, Rajendra P.; Xu, Yong; Saito, Norimichi Journal of the American Chemical Society, 2010 , vol. 132, # 51 p. 18199 - 18205

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   46.15
  • LogP   6.6538
  • H_Acceptors   5
  • H_Donors   0
  • Rotatable_Bonds   13

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