(S)-3,3'-Bis(perfluorophenyl)-[1,1'-binaphthalene]-2,2'-diol

Name: (S)-3,3'-Bis(perfluorophenyl)-[1,1'-binaphthalene]-2,2'-diol
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CAS No. 877304-22-8
Cat. No. CS-0198457
Purity≥97%
MDL No.None

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Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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(S)-3,3'-Bis(perfluorophenyl)-[1,1'-binaphthalene]-2,2'-diol|CS-0198457

Structure of 877304-22-8

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General Information

CAS No. 877304-22-8
Cat. No. CS-0198457
Purity ≥97%
MDL No. None
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₂H₁₂F₁₀O₂
Molecular Weight 618.42
Synonym(s) [1,1'-Binaphthalene]-2,2'-diol, 3,3'-bis(pentafluorophenyl)-, (1S)- (9CI)
SMILES OC1=C(C2=C(O)[C@]([C@](C(F)=C3F)=C(F)C(F)=C3F)=CC4=C2C=CC=C4)C5=C(C=CC=C5)C=C1C6=C(F)C(F)=C(F)C(F)=C6F

Description

This chiral binaphthol derivative features two perfluorophenyl groups at the 3,3'-positions, enhancing electron deficiency and steric bulk. The rigid binaphthyl backbone provides high enantioselectivity, while the diol functionality enables coordination to metals or hydrogen bonding. Designed for asymmetric catalysis and chiral sensing applications, this bench-stable compound integrates readily into complex molecular architectures under standard conditions.

Application

(S)-3,3'-Bis(perfluorophenyl)-[1,1'-binaphthalene]-2,2'-diol serves as a versatile chiral ligand scaffold in asymmetric catalysis, enabling high enantioselectivity in transition-metal-catalyzed reactions. Its rigid binaphthyl framework and electron-deficient perfluorophenyl groups enhance stereocontrol and stability under oxidative conditions. The diol functionality facilitates metal coordination and simplifies purification via crystallization or chromatography, making it suitable for bench-scale synthesis and process development.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 40.46
LogP 9.7962
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 3

Key Words

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(S)-3,3'-Bis(perfluorophenyl)-[1,1'-binaphthalene]-2,2'-diol

CAS No. 877304-22-8

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