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CS-W001157 4
Total: USD 88.00

4-(tert-Butoxycarbonyloxy)styrene,98%(stabilized with TBC)

  • CAS No. 87188-51-0

  • Cat. No. CS-0181406
  • Purity95%(stabilized with TBC)
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

4-(tert-Butoxycarbonyloxy)styrene,98%(stabilized with TBC)|CS-0181406

Structure of 87188-51-0

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General Information

  • CAS No. 87188-51-0
  • Cat. No. CS-0181406
  • Purity 95%(stabilized with TBC)
  • MDL No. None
  • Storage -20°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₃H₁₆O₃
  • Molecular Weight 220.26
  • Synonym(s) Carbonic acid, 1,1-dimethylethyl 4-ethenylphenyl ester
  • SMILES O=C(OC1=CC=C(C=C)C=C1)OC(C)(C)C

Description

4-(tert-Butoxycarbonyloxy)styrene, stabilized with TBC, features a pendant tert-butoxycarbonyl ester group that enables direct incorporation into polymer architectures via radical or transition-metal-catalyzed coupling. The stabilizing TBC inhibitor prevents premature polymerization during storage and handling, ensuring reliable performance in synthetic workflows requiring controlled monomer reactivity.

Application

4-(tert-Butoxycarbonyloxy)styrene, 98% (stabilized with TBC) serves as a versatile building block for the synthesis of functionalized styrenes and heterocyclic scaffolds. The tert-butoxycarbonyl (Boc) protected hydroxyl group enables selective deprotection under mild acidic conditions, while the vinyl functionality supports standard coupling reactions and polymerization processes. Stabilized with tertiary butylcatechol (TBC), it exhibits enhanced bench stability and reduced tendency toward autooxidation, facilitating reliable handling and purification in routine synthetic workflows.

Synthesis

  • Route1

    References

    • E. I. Du Pont de Nemours and Company Patent: US5082965 A1, 1992 ;
  • Route2

    References

    • E. I. Du Pont de Nemours and Company Patent: US5082965 A1, 1992 ;

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

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Computational Chemistry Data

  • TPSA   35.53
  • LogP   3.6435
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   2

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