Methyl 3-fluoropicolinate

Name: Methyl 3-fluoropicolinate
Brand: ChemScene
Availability: InStock
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CAS No. 869108-35-0
Cat. No. CS-0044449
Purity≥98%
MDL No.MFCD06659496

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Structure of 869108-35-0

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General Information

CAS No. 869108-35-0
Cat. No. CS-0044449
Purity ≥98%
MDL No. MFCD06659496
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆FNO₂
Molecular Weight 155.13
Synonym(s) Methyl 3-Fluoropyridine-2-carboxylate
SMILES O=C(C1=NC=CC=C1F)OC

Description

Methyl 3-fluoropicolinate features a fluorinated pyridine ring enabling enhanced electronic effects in synthetic transformations. The ester functionality supports direct derivatization, while the ortho-fluorine imparts metabolic stability and improved binding affinity in medicinal chemistry applications. This bench-stable compound integrates readily into diverse reaction sequences under standard conditions.

Application

Methyl 3-fluoropicolinate serves as a versatile building block in medicinal chemistry, enabling efficient construction of fluorinated heterocycles and bioactive scaffolds. Its electron-deficient pyridine core facilitates nucleophilic substitution and transition-metal-catalyzed coupling reactions. The methyl ester group offers convenient derivatization options, while the 3-fluoro substituent provides enhanced metabolic stability and targeted binding interactions in drug discovery applications. Bench-stable and compatible with standard purification protocols, it functions reliably in multistep syntheses.

Synthesis

Route1
- In-stock
  
  152126-31-3
- 18107-18-1
- ~%
- In-stock
  
  869108-35-0
References
- EP1748048 A1, ; Page/Page column 36 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 39.19
LogP 1.0073
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 3-fluoropicolinate

CAS No. 869108-35-0

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