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CS-W001157 4
Total: USD 88.00

(2R,3S,4S,5R,6R)-2-(Acetoxymethyl)-6-(2,2,2-trichloro-1-iminoethoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate

  • CAS No. 86520-63-0

  • Cat. No. CS-0168539
  • Purity≥97%
  • MDL No.MFCD07369652

*For research and further manufacturing use only, not for direct human use.

(2R,3S,4S,5R,6R)-2-(Acetoxymethyl)-6-(2,2,2-trichloro-1-iminoethoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate|CS-0168539

Structure of 86520-63-0

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General Information

  • CAS No. 86520-63-0
  • Cat. No. CS-0168539
  • Purity ≥97%
  • MDL No. MFCD07369652
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₆H₂₀Cl₃NO₁₀
  • Molecular Weight 492.69
  • Synonym(s) 2,3,4,6-Tetra-O-acetyl-α-D-galactopyranosyl Trichloroacetimidate
  • SMILES CC(O[C@@H]1[C@H]([C@H](O[C@@H]([C@@H]1OC(C)=O)COC(C)=O)OC(C(Cl)(Cl)Cl)=N)OC(C)=O)=O

Synthesis

  • Route1
    • (2R,3R,4S,5R,6R)-2-(Acetoxymethyl)-6-hydroxytetrahydro-2H-pyran-3,4,5-triyl triacetate|CS-0179263
      3947-62-4
    • null|null
      545-06-2
    • ~99%
    • In-stock
      (2R,3S,4S,5R,6R)-2-(Acetoxymethyl)-6-(2,2,2-trichloro-1-iminoethoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate|CS-0168539
      86520-63-0

    References

    • Ban, Lan; Mrksich, Milan Angewandte Chemie - International Edition, 2008 , vol. 47, # 18 p. 3396 - 3399
  • Route2
    • null|null
      70191-05-8
    • null|null
      545-06-2
    • ~92%
    • In-stock
      (2R,3S,4S,5R,6R)-2-(Acetoxymethyl)-6-(2,2,2-trichloro-1-iminoethoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate|CS-0168539
      86520-63-0

    References

    • Pilgrim, Wayne; Murphy, Paul V. Journal of Organic Chemistry, 2010 , vol. 75, # 20 p. 6747 - 6755
  • Route3
    • (2R,3R,4S,5R,6R)-2-(Acetoxymethyl)-6-hydroxytetrahydro-2H-pyran-3,4,5-triyl triacetate|CS-0179263
      3947-62-4
    • null|null
      545-06-2
    • ~39%
    • In-stock
      (2R,3S,4S,5R,6R)-2-(Acetoxymethyl)-6-(2,2,2-trichloro-1-iminoethoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate|CS-0168539
      86520-63-0
    • In-stock
      α-D-Glucopyranose, 2,3,4,6-tetraacetate|CS-0018109
      74808-10-9

    References

    • Carbohydrate Research, , vol. 150, p. 199 - 212

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   147.51
  • LogP   1.43357
  • H_Acceptors   11
  • H_Donors   1
  • Rotatable_Bonds   6

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