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CS-W001157 4
Total: USD 88.00

Tris(4-methoxyphenyl)phosphine

  • CAS No. 855-38-9

  • Cat. No. CS-W014488
  • Purity≥95%
  • MDL No.MFCD00014896

*For research and further manufacturing use only, not for direct human use.

Tris(4-methoxyphenyl)phosphine|CS-W014488

Structure of 855-38-9

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General Information

  • CAS No. 855-38-9
  • Cat. No. CS-W014488
  • Purity ≥95%
  • MDL No. MFCD00014896
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₁H₂₁O₃P
  • Molecular Weight 352.37
  • Synonym(s) Tris(p-anisyl)phosphine
  • SMILES COC1=CC=C(P(C2=CC=C(OC)C=C2)C3=CC=C(OC)C=C3)C=C1

Description

Convenient and selective reagent for the selective formylation of terminal amino groups in such basic amino acids as ornithine or lysine and formylation of α-amino groups in peptides.

Synthesis

  • Route1

    References

    • Kawakubo, Hiromu; Kuroboshi, Manabu; Yano, Tomotake; Kobayashi, Kazuma; Kamenoue, Syogo; Akagi, Tomomi; Tanaka, Hideo Synthesis, 2011 , # 24 art. no. F78211SS, p. 4091 - 4098
  • Route2
    • null|null
      104-92-7
    • ~89%
    • In-stock
      Tris(4-methoxyphenyl)phosphine|CS-W014488
      855-38-9

    References

    • Whitaker, Craig M.; Kott, Kevin L.; McMahon, Robert J. Journal of Organic Chemistry, 1995 , vol. 60, # 11 p. 3499 - 3508
  • Route3
    • null|null
      82303-13-7
    • ~45%
    • In-stock
      Tris(4-methoxyphenyl)phosphine|CS-W014488
      855-38-9

    References

    • Le Gall, Erwan; Ben Aissi, Karima; Lachaise, Isabelle; Troupel, Michel Synlett, 2006 , # 6 p. 954 - 956

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352

Quality Control

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Computational Chemistry Data

  • TPSA   27.69
  • LogP   3.4706
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   6

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