2'-Iodo-1,1':3',1''-terphenyl

Name: 2'-Iodo-1,1':3',1''-terphenyl
Brand: ChemScene
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CAS No. 82777-09-1
Cat. No. CS-0101724
Purity≥98%
MDL No.MFCD00185026

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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2'-Iodo-1,1':3',1''-terphenyl|CS-0101724

Structure of 82777-09-1

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General Information

CAS No. 82777-09-1
Cat. No. CS-0101724
Purity ≥98%
MDL No. MFCD00185026
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₈H₁₃I
Molecular Weight 356.20
Synonym(s) 1-Iodo-2,6-diphenylbenzene
SMILES IC1=C(C2=CC=CC=C2)C=CC=C1C3=CC=CC=C3

Description

2'-Iodo-1,1':3',1''-terphenyl delivers a sterically hindered aryl iodide scaffold with enhanced stability and reactivity in cross-coupling processes. The iodo substituent at the 2'-position enables efficient palladium-catalyzed transformations, while the extended terphenyl framework provides rigidity and electron-rich character. This compound serves as a robust building block for advanced materials and functionalized aromatic systems.

Application

2'-Iodo-1,1':3',1''-terphenyl serves as a versatile building block in cross-coupling chemistry, enabling efficient Suzuki and Stille reactions due to the well-defined reactivity of the iodophenyl group. Its sterically hindered terphenyl framework provides excellent bench stability and facilitates purification, making it ideal for constructing complex aryl architectures in medicinal chemistry and materials science applications.

Synthesis

Route1
- In-stock
  
  92-06-8
- ~%
- In-stock
  
  82777-09-1
References
- Gallego, Daniel; Brueck, Andreas; Irran, Elisabeth; Meier, Florian; Kaupp, Martin; Driess, Matthias; Hartwig, John F. Journal of the American Chemical Society, 2013 , vol. 135, # 41 p. 15617 - 15626
Route2
- In-stock
  
  13402-32-9
- ~%
- In-stock
  
  82777-09-1
References
- Ozasa, Shigeru; Fujioka, Yasuhiro; Kikutake, Jun-ichiro; Ibuki, Eiichi Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 5 p. 1572 - 1581
Route3
- 19625-69-5
- ~%
- In-stock
  
  82777-09-1
References
- Ozasa, Shigeru; Fujioka, Yasuhiro; Kikutake, Jun-ichiro; Ibuki, Eiichi Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 5 p. 1572 - 1581

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07,GHS09
Signal Word : Warning	UN#: 3077
Class : 9	Packing Group : Ⅲ
Hazard Statements : H302-H319-H400-H410
Precautionary Statements : P273-P305+P351+P338-P501

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Computational Chemistry Data

TPSA 0
LogP 5.6252
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Material Science Solar Cell Materials Donor Intermediate DI

Building Blocks Functional Group Iodide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Material Science Material Building Blocks Small Molecule Semiconductor Building Blocks Terphenyls

Key Words

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2'-Iodo-1,1':3',1''-terphenyl

CAS No. 82777-09-1

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