5'-Bromo-1,1':3',1''-terphenyl

Name: 5'-Bromo-1,1':3',1''-terphenyl
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 103068-20-8
Cat. No. CS-W002509
Purity≥97%
MDL No.MFCD00196170

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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5'-Bromo-1,1':3',1''-terphenyl|CS-W002509

Structure of 103068-20-8

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General Information

CAS No. 103068-20-8
Cat. No. CS-W002509
Purity ≥97%
MDL No. MFCD00196170
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₈H₁₃Br
Molecular Weight 309.20
Synonym(s) 3',5'-Diphenylbromobenzene
SMILES Brc1cc(cc(c1)c1ccccc1)c1ccccc1

Description

5'-Bromo-1,1':3',1''-terphenyl features a brominated terphenyl scaffold with enhanced electronic modulation through extended π-conjugation. This bench-stable aryl halide integrates readily into cross-coupling reactions, offering efficient access to functionalized aromatic architectures under standard conditions.

Application

5'-Bromo-1,1':3',1''-terphenyl serves as a versatile building block in cross-coupling reactions, enabling the construction of extended π-conjugated systems. The bromine substituent facilitates reliable Suzuki and Stille couplings under standard conditions, while the terphenyl core provides robust structural rigidity and electronic stability. This compound exhibits excellent bench stability, simplifies purification, and functions effectively in the synthesis of advanced materials and functionalized heterocycles.

Synthesis

Route1
- In-stock
  
  626-39-1
- In-stock
  
  98-80-6
- ~65%
- In-stock
  
  103068-20-8
References
- Matsumoto, Kaya; Hatano, Keiichiro; Umezawa, Naoki; Higuchi, Tsunehiko Synthesis, 2004 , # 13 p. 2181 - 2185
Route2
- 108-86-1
- In-stock
  
  21521-51-7
- ~66%
- In-stock
  
  103068-20-8
References
- BEIJING AGLAIA TECHNOLOGY DEVELOPMENT CO., LTD Patent: US2012/309974 A1, 2012 ; Location in patent: Page/Page column 12 ;
Route3
- In-stock
  
  21521-51-7
- 100-58-3
- ~47%
- In-stock
  
  103068-20-8
References
- SOLVAY SA; MAUNOURY, Jonathan; ORSELLI, Enrico; FERRAND, Alexandre; BASCOUR, Dominique Patent: WO2012/25510 A1, 2012 ; Location in patent: Page/Page column 21 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 0
LogP 5.7831
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Material Science Material Building Blocks Small Molecule Semiconductor Building Blocks Terphenyls

Key Words

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5'-Bromo-1,1':3',1''-terphenyl

CAS No. 103068-20-8

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