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CS-W001157 4
Total: USD 88.00

[1,4-BIs(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

  • CAS No. 79255-71-3

  • Cat. No. CS-W011401
  • Purity≥95%
  • MDL No.MFCD00075219

*For research and further manufacturing use only, not for direct human use.

[1,4-BIs(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate|CS-W011401

Structure of 79255-71-3

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General Information

  • CAS No. 79255-71-3
  • Cat. No. CS-W011401
  • Purity ≥95%
  • MDL No. MFCD00075219
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₆H₄₀P₂Rh.BF₄
  • Molecular Weight 724.36
  • Synonym(s) [Rh(dppb)(COD)]BF4
  • SMILES C[Rh+]1(C)[P](C2=CC=CC=C2)(C3=CC=CC=C3)CCCC[P](C4=CC=CC=C4)1C5=CC=CC=C5.[F-][B+3]([F-])([F-])[F-].C6=C\CC/C=C\CC/6

Description

[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a rhodium-based catalyst used for regioselective hydrogenation and enantioselective reductive amination reactions.[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I)tetrafluoroborate can be used as a catalyst for the:Regioselective hydrogenation of thebaine to synthesize tetrahydrothebaine.Enantioselective reductive amination of -ketoacids with benzylamines to synthesize -N-benzylamino acids.Stereoselective hydrogenation of -(hydroxymethyl)-acrylate derivatives to synthesize 3-hydroxy-2-methylpropanoates.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302+H312+H332-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   N/A
  • H_Donors   N/A
  • Rotatable_Bonds   N/A

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