Rhodium(II) triphenylacetate dimer

Name: Rhodium(II) triphenylacetate dimer
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CAS No. 142214-04-8
Cat. No. CS-0081898
Purity≥97%
MDL No.MFCD15071082

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Rhodium(II) triphenylacetate dimer|CS-0081898

Structure of 142214-04-8

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General Information

CAS No. 142214-04-8
Cat. No. CS-0081898
Purity ≥97%
MDL No. MFCD15071082
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈₀H₆₀O₈Rh₂
Molecular Weight 1355.14
Synonym(s) Rh2(TPA)4
SMILES [Rh+2]1([O-]C(C(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)=[O]5)([O-]C(C(C6=CC=CC=C6)(C7=CC=CC=C7)C8=CC=CC=C8)=[O]9)([O]=C%10C(C%11=CC=CC=C%11)(C%12=CC=CC=C%12)C%13=CC=CC=C%13)[Rh+2]59([O-]%10)[O-]C(C(C%14=CC=CC=C%14)(C%15=CC=CC=C%15)C%16=CC=CC=C%16)=[O]1

Application

Rhodium(II) triphenylacetate dimer serves as a highly effective catalyst for C–H functionalization and cycloaddition reactions, enabling efficient access to nitrogen- and carbon-containing heterocycles. Its robust stability under ambient conditions and compatibility with diverse functional groups facilitate reliable bench-scale synthesis. The dimer functions as a stoichiometric source of Rh₂(II) units, promoting intramolecular [2+2] cycloadditions and enantioselective transformations in established protocols.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS08
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H351
Precautionary Statements : P280-P405-P501

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Computational Chemistry Data

TPSA 40.13
LogP 2.7684
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 4

Other Classifications

Catalysts and Ligands Catalysts Transition Metal Catalysts Rh Catalysts

Catalysis C-H Activation Rhodium Compounds

Catalysis Transition Elements Rhodium

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Chiral Catalysts (Other)

Key Words

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Rhodium(II) triphenylacetate dimer

CAS No. 142214-04-8

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