Tris[4,4'-bis(t-butyl)-2,2'-bipyridine]ruthenium(II) hexafluorophosphate

Name: Tris[4,4'-bis(t-butyl)-2,2'-bipyridine]ruthenium(II) hexafluorophosphate
Brand: ChemScene
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CAS No. 75777-87-6
Cat. No. CS-0084982
Purity≥95%
MDL No.MFCD12022556

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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Tris[4,4'-bis(t-butyl)-2,2'-bipyridine]ruthenium(II) hexafluorophosphate|CS-0084982

Structure of 75777-87-6

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General Information

CAS No. 75777-87-6
Cat. No. CS-0084982
Purity ≥95%
MDL No. MFCD12022556
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅₄H₇₂F₁₂N₆P₂Ru
Molecular Weight 1196.19
Synonym(s) Tris[4,4'-di-tert-butyl-(2,2')-bipyridine]ruthenium(II) dihexafluorophosphate
SMILES CC(C)(C)C1=CC(C2=[N]3C=CC(C(C)(C)C)=C2)=[N]([Ru+2]345([N]6=CC=C(C(C)(C)C)C=C6C7=[N]5C=CC(C(C)(C)C)=C7)[N](C=CC(C(C)(C)C)=C8)=C8C9=CC(C(C)(C)C)=CC=[N]94)C=C1

Application

Tris[4,4'-bis(t-butyl)-2,2'-bipyridine]ruthenium(II) hexafluorophosphate serves as a robust, bench-stable photocatalyst enabling efficient visible-light-driven transformations. Its sterically shielded bipyridine ligands enhance solubility and redox stability, facilitating applications in C–H functionalization, cross-coupling, and photoredox catalysis. The complex exhibits high quantum efficiency and tolerance to diverse functional groups, making it well-suited for scalable synthesis and mechanistic studies.

Safety Information

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GHS Pictogram : N/A	GHS No : N/A
Signal Word : N/A	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

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Tris[4,4'-bis(t-butyl)-2,2'-bipyridine]ruthenium(II) hexafluorophosphate

CAS No. 75777-87-6

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