Tris-(2,2'-bipyridine) ruthenium (II) perchlorate

Name: Tris-(2,2'-bipyridine) ruthenium (II) perchlorate
Brand: ChemScene
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CAS No. 15635-95-7
Cat. No. CS-0084555
Purity≥98%
MDL No.MFCD04974016

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Tris-(2,2'-bipyridine) ruthenium (II) perchlorate|CS-0084555

Structure of 15635-95-7

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General Information

CAS No. 15635-95-7
Cat. No. CS-0084555
Purity ≥98%
MDL No. MFCD04974016
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₀H₂₄Cl₂N₆O₈Ru
Molecular Weight 768.52
Synonym(s) Ru(bpy)3(ClO4)2
SMILES [N]1([Ru+2]234([N]5=CC=CC=C5C6=[N]4C=CC=C6)[N](C=CC=C7)=C7C8=CC=CC=[N]83)=C(C9=[N]2C=CC=C9)C=CC=C1

Description

Tris-(2,2'-bipyridine) ruthenium(II) perchlorate is a luminescent coordination complex featuring three bipyridine ligands chelated to a central Ru²⁺ ion. This robust, bench-stable complex exhibits strong visible light emission and serves as a key photosensitizer in photoredox catalysis and electrochemiluminescence applications.

Application

Tris-(2,2'-bipyridine) ruthenium(II) perchlorate serves as a well-established photosensitizer in homogeneous catalysis and photoredox reactions. Its robust photophysical properties enable efficient visible-light absorption and long-lived excited states, facilitating electron transfer processes in organic synthesis. The complex exhibits high stability under ambient conditions and compatibility with diverse functional groups, making it suitable for bench-scale applications in C–H functionalization, cross-coupling, and cascade transformations.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Key Words

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Tris-(2,2'-bipyridine) ruthenium (II) perchlorate

CAS No. 15635-95-7

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