(S)-Methyl morpholine-3-carboxylate

Name: (S)-Methyl morpholine-3-carboxylate
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CAS No. 741288-31-3
Cat. No. CS-0044006
Purity≥95%
MDL No.MFCD06799487

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(S)-Methyl morpholine-3-carboxylate|CS-0044006

Structure of 741288-31-3

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General Information

CAS No. 741288-31-3
Cat. No. CS-0044006
Purity ≥95%
MDL No. MFCD06799487
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₁₁NO₃
Molecular Weight 145.16
Synonym(s) 3-Morpholinecarboxylicacid,methylester,(3S)-(9CI)
SMILES O=C([C@H]1NCCOC1)OC

Description

(S)-Methyl morpholine-3-carboxylate is a chiral building block featuring a stereodefined morpholine ring with a carboxylate ester at the 3-position. This configuration enables selective incorporation into bioactive molecules, particularly in medicinal chemistry and peptide conjugation workflows where stereocontrol is critical. The compound exhibits bench-stable handling characteristics and compatibility with standard synthetic conditions.

Application

(S)-Methyl morpholine-3-carboxylate serves as a chiral building block for the synthesis of bioactive heterocycles and pharmaceutical intermediates. Its well-defined stereochemistry enables stereoselective transformations in asymmetric synthesis, while the ester functionality offers versatility in downstream modifications. The molecule exhibits excellent bench stability and compatibility with standard reaction conditions, facilitating efficient purification and integration into multi-step synthetic sequences.

Synthesis

Route1
- 1096365-35-3
- ~%
- In-stock
  
  741288-31-3
References
- Organic Letters, , vol. 11, # 2 p. 257 - 260

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 47.56
LogP -0.8522
H_Acceptors 4
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Building Blocks Skeleton Aliphatic heterocycle compounds Morpholine compounds

Key Words

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(S)-Methyl morpholine-3-carboxylate

CAS No. 741288-31-3

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