2'-Hydroxy-6'-methoxyacetophenone

Name: 2'-Hydroxy-6'-methoxyacetophenone
Brand: ChemScene
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CAS No. 703-23-1
Cat. No. CS-W002044
Purity≥98%
MDL No.MFCD00008732

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2'-Hydroxy-6'-methoxyacetophenone|CS-W002044

Structure of 703-23-1

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General Information

CAS No. 703-23-1
Cat. No. CS-W002044
Purity ≥98%
MDL No. MFCD00008732
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₁₀O₃
Molecular Weight 166.17
Synonym(s) 1-(2-Hydroxy-6-methoxyphenyl)ethanone
SMILES COc1cccc(c1C(=O)C)O

Description

2'-Hydroxy-6'-methoxyacetophenone features a strategically positioned hydroxyl group and methoxy substituent on the aromatic ring, enabling enhanced solubility and stability in polar solvents. This electron-rich scaffold facilitates direct integration into complex molecular architectures without requiring protection steps. The ortho-hydroxy functionality supports chelation in metal-catalyzed transformations, while the para-methoxy group modulates electronic properties for tailored reactivity.

Application

2'-Hydroxy-6'-methoxyacetophenone serves as a versatile building block in synthetic organic chemistry, enabling efficient access to substituted benzofurans and other oxygenated heterocycles via intramolecular cyclization. Its ortho-hydroxyl and para-methoxy functionalities provide complementary reactivity for palladium-catalyzed coupling and electrophilic substitution reactions. The compound exhibits excellent bench stability and facilitates straightforward purification, making it well-suited for iterative synthesis workflows in medicinal chemistry and materials science applications.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 46.53
LogP 1.6034
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Ketone

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2'-Hydroxy-6'-methoxyacetophenone

CAS No. 703-23-1

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