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CS-W001157 4
Total: USD 88.00

Adamantanone

  • CAS No. 700-58-3

  • Cat. No. CS-W019662
  • Purity≥98%
  • MDL No.MFCD00074737

*For research and further manufacturing use only, not for direct human use.

Adamantanone|CS-W019662

Structure of 700-58-3

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General Information

  • CAS No. 700-58-3
  • Cat. No. CS-W019662
  • Purity ≥98%
  • MDL No. MFCD00074737
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₄O
  • Molecular Weight 150.22
  • Synonym(s) 2-Adamantone; 2-Oxoadamantane
  • SMILES O=C1[C@H]2C[C@@H]3C[C@@H](C[C@H]1C3)C2

Description

2-Adamantanone on deprotonation in the gas phase affords the corresponding -enolate anion. It reacts with 1,1-dilithio-1-sila-2,3,4,5-tetraphenylsilole to yield 5-silafulvene.2-Adamantanone was used in the synthesis of dispiro N-Boc-protected 1,2,4-trioxane and (+/-)-1-(adamantan-2-yl)-2-propanamine.

Synthesis

  • Route1

    References

    • Yusubov, Mekhman S.; Nemykin, Victor N.; Zhdankin, Viktor V. Tetrahedron, 2010 , vol. 66, # 31 p. 5745 - 5752
  • Route2

    References

    • Mello, Rossella; Fiorentino, Michele; Fusco, Caterina; Curci, Ruggero Journal of the American Chemical Society, 1989 , vol. 111, # 17 p. 6749 - 6757
  • Route3
    • null|null
      23695-65-0
    • ~96%
    • In-stock
      Adamantanone|CS-W019662
      700-58-3

    References

    • Olah; Arvanaghi; Ohannesian; Surya Prakash Synthesis, 1984 , vol. NO. 9, p. 785 - 787

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   17.07
  • LogP   2.0116
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   0

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