2-Chloro-6-methyl-4-nitroaniline

Name: 2-Chloro-6-methyl-4-nitroaniline
Brand: ChemScene
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CAS No. 69951-02-6
Cat. No. CS-0059286
Purity≥95%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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2-Chloro-6-methyl-4-nitroaniline|CS-0059286

Structure of 69951-02-6

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General Information

CAS No. 69951-02-6
Cat. No. CS-0059286
Purity ≥95%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇ClN₂O₂
Molecular Weight 186.60
Synonym(s) 6-CHLORO-4-NITRO-P-TOLUIDINE
SMILES NC1=C(C)C=C([N+]([O-])=O)C=C1Cl

Description

2-Chloro-6-methyl-4-nitroaniline features a nitro group at the para position relative to the amino functionality, imparting strong electron-withdrawing character. The ortho-chloro and meta-methyl substituents provide steric and electronic modulation, enhancing stability under standard conditions. This aniline derivative serves as a key intermediate in the synthesis of dyes, agrochemicals, and pharmaceuticals, where its reactivity profile supports efficient coupling and functionalization.

Application

2-Chloro-6-methyl-4-nitroaniline serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling direct substitution at the aromatic ring due to its complementary electron-withdrawing nitro group and activating chloro/methyl substituents. The molecule exhibits bench stability and facilitates straightforward functionalization via nucleophilic aromatic substitution or transition-metal-catalyzed coupling reactions. Its well-defined reactivity profile supports efficient access to complex heterocyclic scaffolds and drug-like intermediates.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 69.16
LogP 2.13882
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Nitro compounds

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Chloro-6-methyl-4-nitroaniline

CAS No. 69951-02-6

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