6-Bromo-4-methylquinazoline

Name: 6-Bromo-4-methylquinazoline
Brand: ChemScene
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CAS No. 69674-27-7
Cat. No. CS-0233385
Purity≥98%
MDL No.None

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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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General Information

CAS No. 69674-27-7
Cat. No. CS-0233385
Purity ≥98%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₇BrN₂
Molecular Weight 223.07
Synonym(s) 6-bromanyl-4-methyl-quinazoline
SMILES CC1=C2C=C(C=CC2=NC=N1)Br

Description

6-Bromo-4-methylquinazoline is a heterocyclic scaffold featuring a bromine atom at the 6-position and a methyl group at the 4-position, enabling selective functionalization in medicinal chemistry. This electron-deficient core integrates readily into kinase inhibitor designs and serves as a key intermediate for constructing bioactive quinazoline derivatives under standard coupling conditions.

Application

6-Bromo-4-methylquinazoline serves as a versatile building block in medicinal chemistry, enabling palladium-catalyzed cross-coupling reactions for the construction of biaryl and heteroaryl scaffolds. The bromine substituent provides high reactivity in Suzuki, Stille, and Negishi couplings, while the methyl group enhances regiochemical control and metabolic stability. Its bench-stable crystalline form facilitates handling and purification, making it ideal for iterative synthesis campaigns targeting kinase inhibitors and other pharmaceutical candidates.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362-P405-P501

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Computational Chemistry Data

TPSA 25.78
LogP 2.70072
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Quinazoline compounds

Key Words

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6-Bromo-4-methylquinazoline

CAS No. 69674-27-7

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