3-Chloro-1-methylazetidine hydrochloride

Name: 3-Chloro-1-methylazetidine hydrochloride
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CAS No. 69334-72-1
Cat. No. CS-0504631
Purity≥98%
MDL No.None

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Type	HazMat Fee
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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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3-Chloro-1-methylazetidine hydrochloride|CS-0504631

Structure of 69334-72-1

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General Information

CAS No. 69334-72-1
Cat. No. CS-0504631
Purity ≥98%
MDL No. None
Storage Store at room temperature, keep dry and cool
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄H₉Cl₂N
Molecular Weight 142.03
Synonym(s) None
SMILES CN(C1)CC1Cl.Cl

Description

3-Chloro-1-methylazetidine hydrochloride is a bench-stable, moisture-tolerant heterocyclic building block featuring a strained four-membered ring. This sterically accessible azetidinium salt integrates readily into synthetic sequences, enabling efficient incorporation of both chloro and methyl functionalities in medicinal chemistry applications.

Application

3-Chloro-1-methylazetidine hydrochloride serves as a versatile building block in medicinal chemistry, enabling efficient access to bioactive azetidine-containing scaffolds. Its constrained four-membered ring and electrophilic chlorine facilitate nucleophilic substitution reactions under mild conditions, while the protonated amine enhances solubility and simplifies purification. The compound exhibits good bench stability and functional group tolerance, making it suitable for modular synthesis of pharmaceutical intermediates and heterocyclic libraries.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

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Computational Chemistry Data

TPSA 3.24
LogP 0.961
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aliphatic heterocycle compounds Azetidine compounds

Key Words

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3-Chloro-1-methylazetidine hydrochloride

CAS No. 69334-72-1

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