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CS-W001157 4
Total: USD 88.00

N-Benzylcinchonium chloride

  • CAS No. 69221-14-3

  • Cat. No. CS-W011648
  • Purity≥98%
  • MDL No.MFCD00082423

*For research and further manufacturing use only, not for direct human use.

N-Benzylcinchonium chloride|CS-W011648

Structure of 69221-14-3

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General Information

  • CAS No. 69221-14-3
  • Cat. No. CS-W011648
  • Purity ≥98%
  • MDL No. MFCD00082423
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₆H₂₉ClN₂O
  • Molecular Weight 420.98
  • Synonym(s) N-Benzylcinchoninium (chloride)
  • SMILES C=C[C@@H]1[C@](CC2)([H])C[C@H](C(O)C3=CC=NC4=CC=CC=C34)[N@+]2(CC5=CC=CC=C5)C1.[Cl-]

Description

Phase-transfer catalyst involved in:Enantioselective alkylation of malonic diester with alkyl halidesHydrolysis of enol estersAsymmetric 6 electrocyclization for synthesis of functionalized indolinesAsymmetric Michael additionAlkylation of monosubstituted indolinones with alkylhalidesAsymmetric destruction and kinetic resolution of 1-benzylated Reissert compounds

Synthesis

  • Route1
    • null|null
      100-44-7
    • In-stock
      Cinchonine|CS-0008420
      118-10-5
    • ~96%
    • In-stock
      N-Benzylcinchonium chloride|CS-W011648
      69221-14-3

    References

    • Wen, Yeqian; Liang, Mengwei; Wang, Yiming; Ren, Weimin; Lue, Xiaobing Chinese Journal of Chemistry, 2012 , vol. 30, # 9 p. 2109 - 2114

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

Quality Control

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Computational Chemistry Data

  • TPSA   33.12
  • LogP   1.8836
  • H_Acceptors   2
  • H_Donors   1
  • Rotatable_Bonds   5

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