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CS-W001157 4
Total: USD 88.00

1,3-Bis(diphenylphosphino)propane

  • CAS No. 6737-42-4

  • Cat. No. CS-W008852
  • Purity≥98%
  • MDL No.MFCD00003050

*For research and further manufacturing use only, not for direct human use.

1,3-Bis(diphenylphosphino)propane|CS-W008852

Structure of 6737-42-4

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General Information

  • CAS No. 6737-42-4
  • Cat. No. CS-W008852
  • Purity ≥98%
  • MDL No. MFCD00003050
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₇H₂₆P₂
  • Molecular Weight 412.45
  • Synonym(s) 1,3-DPPP
  • SMILES C=1C=CC(=CC1)P(C=2C=CC=CC2)CCCP(C=3C=CC=CC3)C=4C=CC=CC4

Description

1,3-Bis(diphenylphosphino)propane is an organophosphorus compound, that belongs to the class of diphosphine ligands. It is used in transition metal-catalyzed cross-coupling reactions such as Suzuki-Miyaura coupling, Sonogashira coupling, and Negishi coupling reactions. 1,3-Bis(diphenylphosphino)propane is also used in the development of biologically active metal coordination complexes because of its ability to coordinate well with the metals via monodentate or bidentate manner.

Synthesis

  • Route1
    • null|null
      16524-41-7
    • ~93%
    • In-stock
      1,3-Bis(diphenylphosphino)propane|CS-W008852
      6737-42-4

    References

    • Berthod, Mikael; Favre-Reguillon, Alain; Mohamad, Jahjah; Mignani, Gerard; Docherty, Gordon; Lemaire, Marc Synlett, 2007 , # 10 p. 1545 - 1548
  • Route2
    • null|null
      7439-93-2
    • null|null
      142-28-9
    • null|null
      603-35-0
    • ~14%
    • null|null
      1309391-39-6
    • In-stock
      1,3-Bis(diphenylphosphino)propane|CS-W008852
      6737-42-4

    References

    • Journal of Organometallic Chemistry, , vol. 696, # 10 p. 2238 - 2251
  • Route3
    • null|null
      7439-93-2
    • null|null
      142-28-9
    • null|null
      603-35-0
    • ~35%
    • In-stock
      1,3-Bis(diphenylphosphino)propane|CS-W008852
      6737-42-4

    References

    • Shatunov; Korlyukov; Lebedev; Sheludyakov; Kozyrkin; Orlov, V.Yu. Journal of Organometallic Chemistry, 2011 , vol. 696, # 10 p. 2238 - 2251

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   5.6423
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   8

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