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CS-W001157 4
Total: USD 88.00

But-3-en-2-yl acetate,98% stabilized with MEHQ

  • CAS No. 6737-11-7

  • Cat. No. CS-0139597
  • Purity98% (stabilized with MEHQ)
  • MDL No.MFCD00026202

*For research and further manufacturing use only, not for direct human use.

But-3-en-2-yl acetate,98% stabilized with MEHQ|CS-0139597

Structure of 6737-11-7

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General Information

  • CAS No. 6737-11-7
  • Cat. No. CS-0139597
  • Purity 98% (stabilized with MEHQ)
  • MDL No. MFCD00026202
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₆H₁₀O₂
  • Molecular Weight None
  • Synonym(s) aceticacidbutenylester
  • SMILES CC(OC(C=C)C)=O

Description

But-3-en-2-yl acetate, stabilized with MEHQ, is a reactive acrylate ester featuring a terminal vinyl group and a labile acetate moiety. This compound integrates readily into polymerization systems and serves as a key intermediate in synthetic routes requiring selective functionalization under mild conditions.

Application

But-3-en-2-yl acetate, stabilized with MEHQ, serves as a versatile acrylate equivalent in conjugate addition and Michael-type reactions. Its terminal enoate functionality enables reliable coupling with nucleophiles under mild conditions, while the acetate group provides orthogonal reactivity for selective transformations. The stabilizer prevents polymerization during storage and handling, enhancing shelf life and operational safety in synthetic workflows.

Synthesis

  • Route1
    • null|null
      107-01-7
    • null|null
      64-19-7
    • ~%
    • In-stock
      But-3-en-2-yl acetate,98% stabilized with MEHQ|CS-0139597
      6737-11-7
    • null|null
      628-08-0

    References

    • Osaka University; JX NIPPON OIL and ENERGY CORPORATION Patent: US2012/316360 A1, 2012 ; Location in patent: Page/Page column 7-9 ;
  • Route2
    • null|null
      108-05-4
    • null|null
      598-32-3
    • ~72%
    • In-stock
      But-3-en-2-yl acetate,98% stabilized with MEHQ|CS-0139597
      6737-11-7

    References

    • Magens, Silja; Ertelt, Melanie; Jatsch, Anja; Plietker, Bernd Organic Letters, 2008 , vol. 10, # 1 p. 53 - 56
  • Route3
    • null|null
      598-32-3
    • null|null
      75-36-5
    • ~97%
    • In-stock
      But-3-en-2-yl acetate,98% stabilized with MEHQ|CS-0139597
      6737-11-7

    References

    • Vogt, Monika; Ceylan, Sascha; Kirschning, Andreas Tetrahedron, 2010 , vol. 66, # 33 p. 6450 - 6456

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02
Signal Word : Danger
UN#: 1993
Class : 3
Packing Group : Ⅱ
Hazard Statements : H225
Precautionary Statements : P210-P233-P240-P241-P242-P243-P280-P370+P378-P501

Quality Control

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Computational Chemistry Data

  • TPSA   26.3
  • LogP   1.124
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   2

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