3-Bromo-4-(hydroxymethyl)phenol

Name: 3-Bromo-4-(hydroxymethyl)phenol
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CAS No. 666747-04-2
Cat. No. CS-0161059
Purity≥98%
MDL No.MFCD18391433

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3-Bromo-4-(hydroxymethyl)phenol|CS-0161059

Structure of 666747-04-2

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General Information

CAS No. 666747-04-2
Cat. No. CS-0161059
Purity ≥98%
MDL No. MFCD18391433
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇BrO₂
Molecular Weight 203.03
Synonym(s) 3-Bromo-4-hydroxymethyl-phenol
SMILES OC1=CC=C(CO)C(Br)=C1

Description

3-Bromo-4-(hydroxymethyl)phenol features a phenolic hydroxyl group paired with a reactive bromide and a primary alcohol, enabling sequential functionalization in synthetic sequences. This trifunctional scaffold integrates readily into complex architectures via nucleophilic substitution or coupling reactions under mild conditions. The molecule exhibits favorable solubility in common organic solvents and maintains stability during standard bench handling.

Application

3-Bromo-4-(hydroxymethyl)phenol serves as a versatile building block for medicinal chemistry and materials synthesis, enabling efficient functionalization via Suzuki-Miyaura and Stille couplings. The bromo group facilitates palladium-catalyzed cross-coupling, while the hydroxymethyl and phenolic hydroxyl groups offer orthogonal reactivity for derivatization. Bench-stable and readily purified by recrystallization, it functions reliably in multi-step syntheses of bioactive heterocycles and polymer precursors.

Safety Information

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GHS Pictogram : N/A	GHS No : N/A
Signal Word : N/A	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

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Computational Chemistry Data

TPSA 40.46
LogP 1.647
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-4-(hydroxymethyl)phenol

CAS No. 666747-04-2

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