2-Bromo-6-chlorobenzaldehyde

Name: 2-Bromo-6-chlorobenzaldehyde
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 64622-16-8
Cat. No. CS-M3138
Purity≥97%
MDL No.MFCD00266792

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 64622-16-8

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General Information

CAS No. 64622-16-8
Cat. No. CS-M3138
Purity ≥97%
MDL No. MFCD00266792
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₄BrClO
Molecular Weight 219.46
Synonym(s) None
SMILES BrC1=C(C=O)C(Cl)=CC=C1

Description

2-Bromo-6-chlorobenzaldehyde features a sterically unhindered aldehyde group flanked by bromine and chlorine substituents, enabling direct coupling in palladium-catalyzed cross-coupling reactions. This electron-deficient aromatic aldehyde integrates readily into complex molecular architectures under standard conditions.

Application

2-Bromo-6-chlorobenzaldehyde serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling palladium-catalyzed cross-coupling reactions due to its orthogonal halogen reactivity. The aldehyde functionality facilitates downstream transformations such as reductive amination, Wittig reactions, and imine formation, while the bromo and chloro substituents offer complementary sites for selective functionalization. Bench-stable and amenable to purification via crystallization or distillation, it supports scalable synthesis of complex heterocyclic scaffolds and bioactive molecules.

Synthesis

Route1
- In-stock
  
  108-37-2
- 68-12-2
- ~79%
- In-stock
  
  64622-16-8
References
- US2009/118546 A1, ; Page/Page column 6 ;
Route2
- In-stock
  
  62356-27-8
- ~%
- In-stock
  
  64622-16-8
References
- DE213502 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 17.07
LogP 2.915
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Aldehyde

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-6-chlorobenzaldehyde

CAS No. 64622-16-8

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