(R)-2-(3-Chlorophenyl)-2-hydroxyacetic acid

Name: (R)-2-(3-Chlorophenyl)-2-hydroxyacetic acid
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CAS No. 61008-98-8
Cat. No. CS-B1332
Purity≥98%
MDL No.MFCD04038807

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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(R)-2-(3-Chlorophenyl)-2-hydroxyacetic acid|CS-B1332

Structure of 61008-98-8

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General Information

CAS No. 61008-98-8
Cat. No. CS-B1332
Purity ≥98%
MDL No. MFCD04038807
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇ClO₃
Molecular Weight 186.59
Synonym(s) (αR)-3-Chloro-α-hydroxybenzeneacetic acid; (R)-(-)-3-Chloromandelic acid; (R)-(3-Chlorophenyl)hydroxyacetic acid; (2R)-2-(3-Chlorophenyl)-2-Hydroxy-Acetic Acid
SMILES ClC1=CC=CC([C@@H](O)C(O)=O)=C1

Description

(R)-2-(3-Chlorophenyl)-2-hydroxyacetic acid features a chiral center flanked by a hydroxyl group and a 3-chlorophenyl moiety, delivering enhanced stereochemical control in asymmetric synthesis. The electron-withdrawing chlorine substituent stabilizes adjacent carbanions, enabling efficient functionalization under mild conditions. This bench-stable, moisture-tolerant reagent integrates seamlessly into pharmaceutical intermediates and chiral building block workflows.

Application

(R)-2-(3-Chlorophenyl)-2-hydroxyacetic acid serves as a valuable chiral building block for synthesizing pharmaceutical intermediates and bioactive heterocycles. Its well-defined stereochemistry and carboxylic acid functionality enable straightforward derivatization, including esterification and amide coupling, while the ortho-chlorophenyl group provides a handle for further functionalization via cross-coupling reactions. The compound exhibits good bench stability and is readily purified by recrystallization, making it suitable for scalable synthesis workflows.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 57.53
LogP 1.458
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Carboxylic Acid

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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(R)-2-(3-Chlorophenyl)-2-hydroxyacetic acid

CAS No. 61008-98-8

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