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CS-W001157 4
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1,3-Benzodithiolylium tetrafluoroborate

  • CAS No. 57842-27-0

  • Cat. No. CS-0206551
  • Purity≥98%
  • MDL No.MFCD00070613

*For research and further manufacturing use only, not for direct human use.

1,3-Benzodithiolylium tetrafluoroborate|CS-0206551

Structure of 57842-27-0

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General Information

  • CAS No. 57842-27-0
  • Cat. No. CS-0206551
  • Purity ≥98%
  • MDL No. MFCD00070613
  • Storage RT, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₅BF₄S₂
  • Molecular Weight 240.05
  • Synonym(s) None
  • SMILES C1=CC=C2C(=C1)SC=[S+]2.[B-](F)(F)(F)F

Description

1,3-Benzodithiolylium tetrafluoroborate (BDTF, 1,3-BDYT) is an electrophilic compound. It is a salt of 1,3-benzodithiolylium ion.1,3-Benzodithiolylium tetrafluoroborate may be used in the synthesis of the following:Dibenzotetrathiafulvalene by reacting with 1,8-diazabicyclo[5.4.0]undec-7-ene.Substituted arylcarbenium ions by reacting with boronic derivatives.-(1,3-benzodithiol-2-ylidene) ketones and 1,3-benzodithiole by reacting with ketones.2-styryl-1,3-benzodithioles by reacting with styryl-type cobaloximes.2-(3-indolyl)-1,3-benzodithiolylium tetrafluoroborate by reacting with indole.2-(1,3-benzodithiol-2-ylidene)-3,5-cyclohexadien-1-ones and 4-(1,3-benzodithiol-2-ylidene)-2,5-cyclohexadien-1-ones by reacting with 2,4- and 2,6-disubstituted phenols.

Synthesis

  • Route1
    • null|null
      73198-37-5
    • ~89%
    • In-stock
      1,3-Benzodithiolylium tetrafluoroborate|CS-0206551
      57842-27-0

    References

    • Nakayama, Juzo; Fujiwara, Kazuo; Hoshino, Masamatsu Journal of Organic Chemistry, 1980 , vol. 45, p. 2024 - 2025
  • Route2
    • null|null
      55315-56-5
    • ~%
    • In-stock
      1,3-Benzodithiolylium tetrafluoroborate|CS-0206551
      57842-27-0

    References

    • Tetrahedron, , vol. 59, # 33 p. 6353 - 6362

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05,GHS07
Signal Word : Danger
UN#: 1759
Class : 8
Packing Group : Ⅲ
Hazard Statements : H302-H314
Precautionary Statements : P260-P264-P270-P280-P301+P330+P331-P304+P340-P330-P363-P405-P501

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Computational Chemistry Data

  • TPSA   0
  • LogP   4.5439
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   0

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