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CS-W001157 4
Total: USD 88.00

H-D-Gly(allyl)-OH

  • CAS No. 54594-06-8

  • Cat. No. CS-W013623
  • Purity≥97%
  • MDL No.MFCD00063104

*For research and further manufacturing use only, not for direct human use.

H-D-Gly(allyl)-OH|CS-W013623

Structure of 54594-06-8

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General Information

  • CAS No. 54594-06-8
  • Cat. No. CS-W013623
  • Purity ≥97%
  • MDL No. MFCD00063104
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₅H₉NO₂
  • Molecular Weight None
  • Synonym(s) None
  • SMILES C=CC[C@@H](N)C(O)=O

Description

H-D-Gly(allyl)-OH is a protected D-glycine derivative featuring an allyl group at the α-position, enabling orthogonal handling in peptide synthesis. This stable, moisture-tolerant building block integrates seamlessly into N-acylation workflows and facilitates efficient downstream functionalization via click chemistry or palladium-catalyzed transformations.

Synthesis

  • Route1
    • null|null
      1461641-94-0
    • ~67%
    • In-stock
      H-D-Gly(allyl)-OH|CS-W013623
      54594-06-8

    References

    • Sugiyama, Shigeo; Imai, Saori; Ishii, Keitaro Tetrahedron Asymmetry, 2013 , vol. 24, # 18 p. 1069 - 1074
  • Route2
    • null|null
      748740-27-4
    • ~83%
    • In-stock
      H-D-Gly(allyl)-OH|CS-W013623
      54594-06-8

    References

    • Wolf, Larissa B.; Sonke, Theo; Tjen, Kim C. M. F.; Kaptein, Bernard; Broxterman, Quirinus B.; Schoemaker, Hans E.; Rutjes, Floris P. J. T. Advanced Synthesis and Catalysis, 2001 , vol. 343, # 6-7 p. 662 - 674
  • Route3
    • null|null
      1015198-82-9
    • ~76%
    • In-stock
      H-D-Gly(allyl)-OH|CS-W013623
      54594-06-8

    References

    • Sun, Xing-Wen; Liu, Min; Xu, Ming-Hua; Lin, Guo-Qiang Organic Letters, 2008 , vol. 10, # 6 p. 1259 - 1262

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   63.32
  • LogP   -0.0256
  • H_Acceptors   2
  • H_Donors   2
  • Rotatable_Bonds   3

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