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CS-W001157 4
Total: USD 88.00

7,7-Dichlorobicyclo[3.2.0]hept-2-en-6-one

  • CAS No. 5307-99-3

  • Cat. No. CS-0040451
  • Purity≥97%
  • MDL No.MFCD16621736

*For research and further manufacturing use only, not for direct human use.

7,7-Dichlorobicyclo[3.2.0]hept-2-en-6-one|CS-0040451

Structure of 5307-99-3

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General Information

  • CAS No. 5307-99-3
  • Cat. No. CS-0040451
  • Purity ≥97%
  • MDL No. MFCD16621736
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₆Cl₂O
  • Molecular Weight 177.03
  • Synonym(s) Dichlorobicycloheptenone
  • SMILES O=C1C2CC=CC2C1(Cl)Cl

Description

7,7-Dichlorobicyclo[3.2.0]hept-2-en-6-one features a rigid bicyclic framework with two chlorine atoms at the bridgehead position, imparting high stability and distinct electronic properties. The enone functionality enables participation in Michael additions and Diels-Alder reactions, while the dichloro substitution enhances electrophilicity at the carbonyl carbon. This compound serves as a valuable scaffold for synthetic access to complex polycyclic architectures in medicinal chemistry and natural product synthesis.

Synthesis

  • Route1
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      79-36-7
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      542-92-7
    • ~88%
    • In-stock
      7,7-Dichlorobicyclo[3.2.0]hept-2-en-6-one|CS-0040451
      5307-99-3

    References

    • Baya, Mounir; Soulounganga, Patrice; Gelhaye, Eric; Grardin, Philippe Pest Management Science, 2001 , vol. 57, # 9 p. 833 - 838
  • Route2
    • null|null
      542-92-7
    • null|null
      76-02-8
    • ~62%
    • In-stock
      7,7-Dichlorobicyclo[3.2.0]hept-2-en-6-one|CS-0040451
      5307-99-3

    References

    • Ussing, Bryson R.; Hang, Chao; Singleton, Daniel A. Journal of the American Chemical Society, 2006 , vol. 128, # 23 p. 7594 - 7607
  • Route3
    • null|null
      20618-08-0
    • null|null
      542-92-7
    • ~86%
    • In-stock
      7,7-Dichlorobicyclo[3.2.0]hept-2-en-6-one|CS-0040451
      5307-99-3

    References

    • Depres; Greene; Crabbe Tetrahedron, 1981 , vol. 37, # 3 p. 621 - 628

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05,GHS07
Signal Word : Danger
UN#: 3265
Class : 8
Packing Group : Ⅲ
Hazard Statements : H302-H314
Precautionary Statements : P260-P264-P270-P280-P301+P330+P331-P304+P340-P330-P363-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   17.07
  • LogP   1.9353
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   0

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