2-Amino-5-chlorobenzamide

Name: 2-Amino-5-chlorobenzamide
Brand: ChemScene
Availability: InStock
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CAS No. 5202-85-7
Cat. No. CS-W017670
Purity≥98%
MDL No.MFCD00017126
AREC Toxic Substance

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 5202-85-7
Cat. No. CS-W017670
Purity ≥98%
MDL No. MFCD00017126
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇ClN₂O
Molecular Weight 170.60
Synonym(s) 5-Chloroanthranilamide
SMILES NC(C1=C(C=CC(Cl)=C1)N)=O

Description

2-Amino-5-chlorobenzamide delivers a strategically positioned chloro group and amino functionality for targeted coupling reactions. This electron-rich scaffold integrates readily into pharmaceutical intermediates, offering enhanced solubility and stability under standard conditions. The para-chloro substitution enables selective functionalization in synthetic sequences.

Application

2-Amino-5-chlorobenzamide serves as a versatile building block in medicinal chemistry, enabling the construction of diverse heterocyclic scaffolds through amide coupling and electrophilic substitution reactions. Its ortho-amino and chloro substituents offer complementary reactivity for sequential functionalization, while its bench-stable crystalline form facilitates handling and purification. The molecule functions effectively in standard peptide synthesis protocols and supports the development of kinase inhibitors and other bioactive compounds.

Synthesis

Route1
- In-stock
  
  4743-17-3
- ~86%
- In-stock
  
  5202-85-7
References
- Mohiuddin, Ghulam; Reddy, Padala Satyanarayana; Ahmed, Khalil; Ratnam, Chengalvala Venkata Journal of Chemical Research, Miniprint, 1987 , # 7 p. 1839 - 1868
Route2
- In-stock
  
  34662-31-2
- ~69%
- In-stock
  
  5202-85-7
References
- Blackie, Josie A.; Turner, Nicholas J.; Wells, Andrew S. Tetrahedron Letters, 1997 , vol. 38, # 17 p. 3043 - 3046
Route3
- In-stock
  
  40763-96-0
- 7439-89-6
- ~99%
- In-stock
  
  5202-85-7
References
- American Home Products Corporation Patent: US5187168 A1, 1993 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 69.11
LogP 1.0211
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Amide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

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2-Amino-5-chlorobenzamide

CAS No. 5202-85-7

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