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CS-W001157 4
Total: USD 88.00

exo-2-Norborneol

  • CAS No. 497-37-0

  • Cat. No. CS-0063194
  • Purity≥96%
  • MDL No.MFCD00136051

*For research and further manufacturing use only, not for direct human use.

exo-2-Norborneol|CS-0063194

Structure of 497-37-0

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General Information

  • CAS No. 497-37-0
  • Cat. No. CS-0063194
  • Purity ≥96%
  • MDL No. MFCD00136051
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₁₂O
  • Molecular Weight 112.17
  • Synonym(s) None
  • SMILES O[C@H]1[C@](C2)([H])CC[C@]2([H])C1

Description

exo-Norborneol was used in the synthesis of cyclic ketones.

Application

exo-2-Norborneol serves as a valuable chiral building block in synthetic organic chemistry, leveraging its rigid bicyclic structure and well-defined stereochemistry. The exo-hydroxyl group enables reliable functionalization in standard transformations, including esterification, etherification, and oxidation, with high diastereoselectivity. Its bench stability and ease of purification make it suitable for applications in asymmetric synthesis, catalytic reactions, and the construction of complex heterocyclic scaffolds.

Synthesis

  • Route1
    • (1R,2S,4R,5S)-3-Oxatricyclo[3.2.1.02,4]octane|CS-1639799
      844874-18-6
    • ~78%
    • In-stock
      exo-2-Norborneol|CS-0063194
      497-37-0

    References

    • Kim, Sunggak; Ahn, Kyo Han Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1717 - 1724
  • Route2

    References

    • Khusnutdinov; Oshnyakova; Shchadneva Russian Journal of Organic Chemistry, 2013 , vol. 49, # 10 p. 1428 - 1432 Zhurnal Organicheskoi Khimii, 2013 , vol. 49, # 10 p. 1451 - 1455,5
  • Route3

    References

    • Clerici, Angelo; Pastori, Nadia; Porta, Ombretta European Journal of Organic Chemistry, 2001 , # 12 p. 2235 - 2243

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   20.23
  • LogP   1.1673
  • H_Acceptors   1
  • H_Donors   1
  • Rotatable_Bonds   0

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