[2,2'-Bipyridine]-3,3'-dicarboxylic acid

Name: [2,2'-Bipyridine]-3,3'-dicarboxylic acid
Brand: ChemScene
Availability: InStock
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CAS No. 4433-01-6
Cat. No. CS-W004579
Purity≥97%
MDL No.MFCD00226068

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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[2,2'-Bipyridine]-3,3'-dicarboxylic acid|CS-W004579

Structure of 4433-01-6

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Description

This bipyridine derivative features two carboxylic acid groups at the 3 and 3' positions, enabling strong metal chelation and coordination in transition metal complexes. The electron-deficient pyridine rings facilitate redox activity and enhance binding affinity for lanthanides and actinides. Designed for stability under standard conditions, it integrates readily into supramolecular architectures and functional materials.

Application

[2,2'-Bipyridine]-3,3'-dicarboxylic acid serves as a versatile chelating ligand in transition metal catalysis, enabling stable coordination to metals such as ruthenium and iron. Its dual carboxylic acid groups enhance solubility and facilitate purification, while the bipyridine core provides robust π-acceptor character. Functions effectively in homogeneous catalytic systems and as a building block for coordination polymers and photoactive materials.

General Information

CAS No. 4433-01-6
Cat. No. CS-W004579
Purity ≥97%
MDL No. MFCD00226068
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₈N₂O₄
Molecular Weight 244.21
Synonym(s) Acide 2,2'-bipyridine-3,3'-dicarboxylique
SMILES O=C(O)C1=CC=CN=C1C=2N=CC=CC2C(=O)O

Computational Chemistry Data

TPSA 100.38
LogP 1.54
H_Acceptors 4
H_Donors 2
Rotatable_Bonds 3

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

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Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Bipyridine Ligands

Material Science Material Building Blocks Ligands for Functional Metal Complexes Bipyridine Ligands, Terpyridine Ligands

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Bipyridine Ligands, Terpyridine Ligands

Key Words

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[2,2'-Bipyridine]-3,3'-dicarboxylic acid

CAS No. 4433-01-6

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