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CS-W001157 4
Total: USD 88.00

Bis(1,5-cyclooctadiene)(duroquinone)nickel

  • CAS No. 40759-64-6

  • Cat. No. CS-0188823
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

Bis(1,5-cyclooctadiene)(duroquinone)nickel|CS-0188823

Structure of 40759-64-6

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General Information

  • CAS No. 40759-64-6
  • Cat. No. CS-0188823
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₈H₂₀NiO₂
  • Molecular Weight 327.05
  • Synonym(s) C10H12O2NiC8H12-1,5-cyclo
  • SMILES O=C(C(C)=C1C)C(C)=C(C)C1=O.C[Ni](C)(C)C.C2C/C=C\CC/C=C\2

Application

Bis(1,5-cyclooctadiene)(duroquinone)nickel serves as a stable, air-tolerant precatalyst for cross-coupling reactions, enabling efficient Ni-catalyzed C–C and C–heteroatom bond formations. The duroquinone ligand enhances catalyst longevity and facilitates oxidative addition with aryl halides and pseudohalides. Its bench-stable nature and compatibility with diverse functional groups make it ideal for iterative synthesis workflows in medicinal chemistry and materials science.

Safety Information

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GHS Pictogram :
GHS No : GHS02,GHS07,GHS08
Signal Word : Danger
UN#: 1325
Class : 4.1
Packing Group : Ⅱ
Hazard Statements : H228-H302-H317-H334-H350-H372
Precautionary Statements : P210-P240-P241-P260-P261-P264-P270-P272-P280-P284-P302+P352-P304+P340-P330-P362+P364-P370+P378-P405-P501

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Computational Chemistry Data

  • TPSA   34.14
  • LogP   6.8165
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   0

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