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CS-W001157 4
Total: USD 88.00

Ni(COD)2

  • CAS No. 1295-35-8

  • Cat. No. CS-0035192
  • Purity≥97%
  • MDL No.MFCD00058902

*For research and further manufacturing use only, not for direct human use.

Ni(COD)2|CS-0035192

Structure of 1295-35-8

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General Information

  • CAS No. 1295-35-8
  • Cat. No. CS-0035192
  • Purity ≥97%
  • MDL No. MFCD00058902
  • Storage -20°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₆H₂₄Ni
  • Molecular Weight 275.06
  • Synonym(s) Nickel, bis(1,5-cyclooctadiene)-
  • SMILES C1=C\CC/C=C\CC/1.C2=C\CC/C=C\CC/2.[Ni]

Description

Reactant for:Oxidative addition reactionsCatalyst for:Asymmetric -arylation and heteroarylation of ketones with chloroarenesCross-coupling reactionsRegioselective and stereoselective carboxylation/cyclization of allenyl aldehydes under a carbon dioxide atmosphereMethyl carboxylation of homopropargylic alcoholsStereoselective borylative ketone-diene couplingCycloaddition of benzamides with internal alkynes

Synthesis

  • Route1
    • In-stock
      Dichlorotetrakis(pyridine)nickel|CS-0198929
      14076-99-4
    • null|null
      5259-72-3
    • ~81%
    • In-stock
      Ni(COD)2|CS-0035192
      1295-35-8

    References

    • Tenorio, Manuel Jimenez; Puerta, M. Carmen; Salcedo, Isabel; Valegra, Pedro Journal of the Chemical Society, Dalton Transactions, 2001 , p. 653 - 657
  • Route2
    • null|null
      112679-75-1
    • null|null
      5259-72-3
    • ~60%
    • In-stock
      Ni(COD)2|CS-0035192
      1295-35-8

    References

    • Schroeder, Wolfgang; Poerschke, Klaus R. Journal of Organometallic Chemistry, 1987 , vol. 322, p. 385 - 392
  • Route3
    • null|null
      50696-82-7
    • null|null
      5259-72-3
    • ~%
    • In-stock
      Ni(COD)2|CS-0035192
      1295-35-8

    References

    • Angewandte Chemie, , vol. 85, p. 620 - 621 Diss. Bochum 1973

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS08
Signal Word : Danger
UN#: 1325
Class : 4.1
Packing Group : Ⅱ
Hazard Statements : H228-H334-H351
Precautionary Statements : P201-P202-P210-P240-P241-P261-P270-P280-P285-P304+P341-P308+P313-P342+P311-P370+P378-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   5.3431
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   0

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