Methyl 3-chloro-4-hydroxybenzoate

Name: Methyl 3-chloro-4-hydroxybenzoate
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CAS No. 3964-57-6
Cat. No. CS-W007871
Purity≥97%
MDL No.MFCD00016418

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Methyl 3-chloro-4-hydroxybenzoate|CS-W007871

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Description

Methyl 3-chloro-4-hydroxybenzoate features a chlorinated aromatic ring bearing both hydroxyl and ester functionalities, enabling selective derivatization in synthetic pathways. The para-hydroxy group enhances solubility and reactivity, while the ortho-chlorine imparts electronic modulation. This compound serves as a key intermediate in pharmaceutical and agrochemical synthesis, particularly where halogenated phenolic motifs are required.

Application

Methyl 3-chloro-4-hydroxybenzoate serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient access to substituted benzene scaffolds. The ortho-chloro and phenolic hydroxyl groups provide orthogonal reactivity for downstream functionalization via nucleophilic substitution or coupling reactions. Its bench-stable nature and compatibility with standard purification methods facilitate integration into multi-step synthetic sequences.

General Information

CAS No. 3964-57-6
Cat. No. CS-W007871
Purity ≥97%
MDL No. MFCD00016418
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇ClO₃
Molecular Weight 186.59
Synonym(s) METHYL-4-HYDROXY-3-CHLOROBENZOATE; Methyl 3-chloro-4-hydroxybenzoate
SMILES O=C(OC)C1=CC=C(O)C(Cl)=C1

Computational Chemistry Data

TPSA 46.53
LogP 1.8322
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Methyl 3-chloro-4-hydroxybenzoate

CAS No. 3964-57-6

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