Phenyl N-hydroxycarbamate

Name: Phenyl N-hydroxycarbamate
Brand: ChemScene
Availability: InStock
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CAS No. 38064-07-2
Cat. No. CS-0199118
Molecule weight153.14
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 38064-07-2

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General Information

CAS No. 38064-07-2
Cat. No. CS-0199118
Purity ≥97%
MDL No. None
Storage 4°C, sealed storage, away from moisture
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇NO₃
Molecular Weight 153.14
Synonym(s) PhenylN-hydroxycarbamate
SMILES ONC(OC1=CC=CC=C1)=O

Description

Phenyl N-hydroxycarbamate serves as a stable, bench-ready reagent for selective O-amination reactions. The hydroxycarbamate moiety enables efficient coupling with electrophilic substrates under mild conditions, offering a reliable route to oxime derivatives. This reagent integrates seamlessly into synthetic workflows requiring controlled nitrogen transfer.

Application

Phenyl N-hydroxycarbamate serves as a stable, bench-ready precursor for hydroxylamine transfer in synthetic transformations. It facilitates efficient O-alkylation and oxime formation under mild conditions, demonstrating broad functional group tolerance. Its crystalline nature enables straightforward isolation and purification, making it well-suited for iterative synthesis workflows. This reagent functions reliably in the construction of heterocyclic scaffolds and amidoxime intermediates within standard organic protocols.

Synthesis

Route1
- 1885-14-9
- ~89%
- In-stock
  
  38064-07-2
References
- Defoin, Albert; Brouillard-Poichet, Agnes; Streith, Jacques Helvetica Chimica Acta, 1992 , vol. 75, # 1 p. 109 - 123
Route2
- In-stock
  
  102-09-0
- ~61%
- In-stock
  
  38064-07-2
References
- Defoin, Albert; Brouillard-Poichet, Agnes; Streith, Jacques Helvetica Chimica Acta, 1992 , vol. 75, # 1 p. 109 - 123

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362-P405-P501

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Computational Chemistry Data

TPSA 58.56
LogP 1.1642
H_Acceptors 3
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

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Phenyl N-hydroxycarbamate

CAS No. 38064-07-2

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