3-Bromo-2-hydroxy-6-picoline

Name: 3-Bromo-2-hydroxy-6-picoline
Brand: ChemScene
Availability: InStock
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CAS No. 374633-33-7
Cat. No. CS-0034716
Purity≥97%
MDL No.MFCD03095217

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HazMat Fee

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Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

Structure of 374633-33-7

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Description

3-Bromo-2-hydroxy-6-picoline features a bromine substituent at the 3-position and a hydroxyl group at the 2-position on a picoline scaffold, delivering a uniquely reactive site for nucleophilic substitution and functionalization. This bench-stable, moisture-tolerant compound integrates readily into synthetic sequences requiring selective C–Br activation or orthogonal protection strategies.

Application

3-Bromo-2-hydroxy-6-picoline serves as a versatile building block for heterocyclic synthesis, enabling efficient access to substituted pyridine scaffolds. The bromo group facilitates palladium-catalyzed cross-coupling reactions, while the adjacent hydroxyl group offers orthogonal functionalization potential. Its bench-stable nature and compatibility with standard purification methods make it well-suited for medicinal chemistry campaigns and process development workflows.

General Information

CAS No. 374633-33-7
Cat. No. CS-0034716
Purity ≥97%
MDL No. MFCD03095217
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₆BrNO
Molecular Weight 188.02
Synonym(s) 5-Bromo-6-hydroxy-2-picoline
SMILES O=C1C(Br)=CC=C(C)N1

Computational Chemistry Data

TPSA 32.86
LogP 1.44582
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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3-Bromo-2-hydroxy-6-picoline

CAS No. 374633-33-7

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