Methyl 4-chloro-3-iodobenzoate

Name: Methyl 4-chloro-3-iodobenzoate
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CAS No. 365526-34-7
Cat. No. CS-0094444
Purity≥96%
MDL No.MFCD09263357

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 4-chloro-3-iodobenzoate|CS-0094444

Structure of 365526-34-7

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General Information

CAS No. 365526-34-7
Cat. No. CS-0094444
Purity ≥96%
MDL No. MFCD09263357
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₆ClIO₂
Molecular Weight 296.49
Synonym(s) Methyl 3-Iodo-4-chlorobenzoate
SMILES O=C(OC)C1=CC=C(Cl)C(I)=C1

Description

Methyl 4-chloro-3-iodobenzoate features a sterically accessible ortho-iodo group paired with a bench-stable ester functionality, enabling direct cross-coupling and functionalization in late-stage diversification. The electron-deficient aromatic core supports palladium-catalyzed transformations under standard conditions.

Application

Methyl 4-chloro-3-iodobenzoate serves as a versatile building block in transition-metal-catalyzed cross-coupling reactions, enabling efficient access to substituted biaryls and heterocycles. The ortho-iodo and meta-chloro groups provide orthogonal reactivity for sequential functionalization. Its bench-stable nature and compatibility with Pd(0) catalysis facilitate reliable synthesis of complex aromatic scaffolds under standard conditions.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 26.3
LogP 2.7312
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Methyl 4-chloro-3-iodobenzoate

CAS No. 365526-34-7

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