5-Bromo-4-hydroxy-6-methylpyrimidine

Name: 5-Bromo-4-hydroxy-6-methylpyrimidine
Brand: ChemScene
Availability: InStock
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CAS No. 3438-52-6
Cat. No. CS-W002804
Purity≥95%
MDL No.MFCD01646062

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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5-Bromo-4-hydroxy-6-methylpyrimidine|CS-W002804

Structure of 3438-52-6

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General Information

CAS No. 3438-52-6
Cat. No. CS-W002804
Purity ≥95%
MDL No. MFCD01646062
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅H₅BrN₂O
Molecular Weight 189.01
Synonym(s) 5-Bromo-6-methylpyrimidin-4-OL
SMILES Brc1c(C)ncnc1O

Description

5-Bromo-4-hydroxy-6-methylpyrimidine features a strategically positioned bromo group and hydroxyl moiety on a pyrimidine scaffold, enabling direct functionalization in cross-coupling and derivatization workflows. The methyl substituent enhances solubility and stability under standard conditions. This heterocycle serves as a key intermediate for bioactive molecule synthesis.

Application

5-Bromo-4-hydroxy-6-methylpyrimidine serves as a versatile building block in heterocyclic synthesis, enabling direct functionalization at the C4 hydroxyl and C5 bromine positions. Its stability under standard reaction conditions facilitates efficient coupling reactions and nucleophilic substitutions. The methyl group enhances solubility and provides a handle for further derivatization. This compound functions reliably in the construction of pyrimidine-based scaffolds relevant to medicinal chemistry and agrochemical development.

Synthesis

Route1
- In-stock
  
  3524-87-6
- ~91%
- In-stock
  
  3438-52-6
References
- Wang, Zhihan; Chi, Yushi; Harris, Anthony R.; Gray, David; Davoren, Jennifer E. Synthesis, 2011 , # 10 art. no. M25011SS, p. 1529 - 1531

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 46.01
LogP 1.25312
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Pyrimidine compounds

Key Words

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5-Bromo-4-hydroxy-6-methylpyrimidine

CAS No. 3438-52-6

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