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CS-W001157 4
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2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl

  • CAS No. 3225-26-1

  • Cat. No. CS-0186472
  • Purity≥96%
  • MDL No.MFCD00075563

*For research and further manufacturing use only, not for direct human use.

2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl|CS-0186472

Structure of 3225-26-1

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General Information

  • CAS No. 3225-26-1
  • Cat. No. CS-0186472
  • Purity ≥96%
  • MDL No. MFCD00075563
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₆H₂₂NO₃
  • Molecular Weight 276.35
  • Synonym(s) 4-Hydroxy-TEMPO-benzoate
  • SMILES CC1(CC(OC(C2=CC=CC=C2)=O)CC(C)([N+]1[O-])C)C

Description

4-Hydroxy-TEMPO benzoate is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative.4-Hydroxy-TEMPO benzoate was employed as spin probe to investigate the mechanism of synthesis of SBA-15 and to evaluate its surface properties and pore structure by electron paramagnetic resonance spectroscopy (EPR). It was also used for the functionalization of various polydienes (polybutadiene and polyisoprene). Functionalized polydienes were analyzed by gel permeation chromatography.

Synthesis

  • Route1

    References

    • Zakrzewski, Jerzy Monatshefte fuer Chemie, 1990 , vol. 121, # 10 p. 803 - 808
  • Route2
    • null|null
      45985-24-8
    • In-stock
      Benzoic acid|CS-0008257
      65-85-0
    • ~%
    • In-stock
      2,2,6,6-Tetramethyl-4-(benzoyloxy)piperidine-1-oxyl|CS-0186472
      3225-26-1

    References

    • Advanced Synthesis and Catalysis, , vol. 352, # 1 p. 113 - 118
  • Route3

    References

    • Helvetica Chimica Acta, , vol. 63, # 1 p. 132 - 147

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

  • TPSA   55.26
  • LogP   3.2009
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   2

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