2-Bromo-4-fluoro-6-nitrophenol

Name: 2-Bromo-4-fluoro-6-nitrophenol
Brand: ChemScene
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CAS No. 320-75-2
Cat. No. CS-0036370
Purity≥98%
MDL No.MFCD03094182

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Bromo-4-fluoro-6-nitrophenol|CS-0036370

Structure of 320-75-2

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General Information

CAS No. 320-75-2
Cat. No. CS-0036370
Purity ≥98%
MDL No. MFCD03094182
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₃BrFNO₃
Molecular Weight None
Synonym(s) 6-Bromo-4-fluoro-2-nitrophenol
SMILES C1=C(C=C(C(=C1Br)O)[N+](=O)[O-])F

Description

2-Bromo-4-fluoro-6-nitrophenol features a trifunctional aromatic core with bromine, fluorine, and nitro groups positioned for orthogonal reactivity. This electron-deficient phenol integrates readily into cross-coupling cascades and serves as a key intermediate in the synthesis of bioactive heterocycles and functional materials.

Application

2-Bromo-4-fluoro-6-nitrophenol serves as a versatile building block in the synthesis of functionalized heterocycles and pharmaceutical intermediates. Its orthogonal reactivity profile—combining electrophilic bromination, nucleophilic fluorination, and nitro group reduction—enables selective transformations under standard conditions. The compound exhibits good bench stability and facilitates efficient coupling reactions, making it well-suited for iterative synthetic sequences in medicinal chemistry and process development.

Safety Information

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GHS Pictogram : N/A	GHS No : N/A
Signal Word : N/A	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

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Computational Chemistry Data

TPSA 63.37
LogP 2.202
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Fluoride

Building Blocks Functional Group Nitro compounds

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-4-fluoro-6-nitrophenol

CAS No. 320-75-2

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