Methyl 4-chlorobutanoate

Name: Methyl 4-chlorobutanoate
Brand: ChemScene
Availability: InStock
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CAS No. 3153-37-5
Cat. No. CS-0001466
Purity≥95%
MDL No.MFCD00001003

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 3153-37-5

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General Information

CAS No. 3153-37-5
Cat. No. CS-0001466
Purity ≥95%
MDL No. MFCD00001003
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅H₉ClO₂
Molecular Weight None
Synonym(s) Methyl 4-chlorobutyrate; Methyl 4-chlorobutanoate
SMILES O=C(OC)CCCCl

Description

Methyl 4-chlorobutanoate serves as a key synthetic intermediate in the construction of bioactive molecules and functional polymers. This ester features a chlorine-substituted aliphatic chain, enabling efficient incorporation into diverse reaction cascades. The molecule exhibits favorable stability under standard conditions and demonstrates good solubility in common organic solvents, facilitating its use in multistep synthesis workflows.

Application

Methyl 4-chlorobutanoate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to γ-chloroester intermediates. Its well-established reactivity facilitates nucleophilic substitution and subsequent transformations in the synthesis of bioactive molecules. The ester functionality offers excellent bench stability and ease of purification, while the α-chloroalkyl group enables selective functionalization under mild conditions. This compound functions effectively in multistep sequences for heterocyclic and pharmaceutical scaffold construction.

Synthesis

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- 28341-54-0
- ~%
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  3153-37-5
References
- Justus Liebigs Annalen der Chemie, , vol. 596, p. 162,182
Route2
- 61882-39-1
- ~%
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  3153-37-5
References
- Journal of the American Chemical Society, , vol. 63, p. 2489
Route3
- 7719-09-7
- In-stock
  
  29006-02-8
- ~%
- In-stock
  
  3153-37-5
References
- Journal of the American Chemical Society, , vol. 63, p. 2489

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS02
Signal Word : Danger	UN#: 3272
Class : 3	Packing Group : Ⅲ
Hazard Statements : H226
Precautionary Statements : P210-P233-P240-P241-P242-P243

Quality Control

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Computational Chemistry Data

TPSA 26.3
LogP 1.1784
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 3

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Ester

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Methyl 4-chlorobutanoate

CAS No. 3153-37-5

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