7-Bromo-4-fluoro-1H-indole

Name: 7-Bromo-4-fluoro-1H-indole
Brand: ChemScene
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CAS No. 292636-09-0
Cat. No. CS-W008409
Purity≥96%
MDL No.MFCD04037874

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 292636-09-0
Cat. No. CS-W008409
Purity ≥96%
MDL No. MFCD04037874
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₅BrFN
Molecular Weight 214.03
Synonym(s) 7-BROMO-4-FLUOROINDOLE
SMILES FC1=CC=C(Br)C2=C1C=CN2

Description

7-Bromo-4-fluoro-1H-indole features a halogenated indole scaffold with strategic bromine and fluorine substituents at the 7- and 4-positions, respectively. This electron-deficient heterocycle integrates readily into transition-metal-catalyzed coupling reactions, enabling efficient access to complex molecular architectures in medicinal chemistry and materials science.

Application

7-Bromo-4-fluoro-1H-indole serves as a valuable building block for the synthesis of biologically active heterocycles, enabling direct functionalization at the 3-position via palladium-catalyzed cross-coupling. The ortho-halogen substitution pattern facilitates regioselective transformations, while the fluorine substituent enhances metabolic stability and modulates electronic properties. Bench-stable and compatible with standard synthetic workflows, it functions effectively in Suzuki-Miyaura, Stille, and Negishi coupling reactions.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 15.79
LogP 3.0695
H_Acceptors 0
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Indole compounds

Key Words

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7-Bromo-4-fluoro-1H-indole

CAS No. 292636-09-0

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