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CS-W001157 4
Total: USD 88.00

Diethyl 2-bromo-2-methylmalonate

  • CAS No. 29263-94-3

  • Cat. No. CS-W001079
  • Purity≥98%
  • MDL No.MFCD00009125

*For research and further manufacturing use only, not for direct human use.

Diethyl 2-bromo-2-methylmalonate|CS-W001079

Structure of 29263-94-3

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General Information

  • CAS No. 29263-94-3
  • Cat. No. CS-W001079
  • Purity ≥98%
  • MDL No. MFCD00009125
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₁₃BrO₄
  • Molecular Weight 253.09
  • Synonym(s) Diethyl-2-bromo-2-methyl malonate
  • SMILES CCOC(=O)C(C(=O)OCC)(Br)C

Description

Diethyl 2-bromo-2-methylmalonate acts as initiator during the atom transfer radical polymerization of methyl methacrylate.Diethyl 2-bromo-2-methylmalonate was used to investigate the 1,2,2,6,6-pentamethylpiperidine as an effective reducing agent for the radical chain conversion of primary bromoesters to the corresponding esters. It was used in the synthesis of polystyrene macroinitiator via atom transfer radical polymerization.

Synthesis

  • Route1

    References

    • Suzuki, Yoshitada; Kodomari, Mitsuo Chemistry Letters, 1998 , # 11 p. 1091 - 1092

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 3265
Class : 8
Packing Group : Ⅱ
Hazard Statements : H314-H318
Precautionary Statements : P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501

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Computational Chemistry Data

  • TPSA   52.6
  • LogP   1.2662
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   4

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