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CS-W001157 4
Total: USD 88.00

2-(Allyloxy)benzaldehyde,98% stabilized with MEHQ

  • CAS No. 28752-82-1

  • Cat. No. CS-W016117
  • Purity96% (stabilized with MEHQ)
  • MDL No.MFCD00014130

*For research and further manufacturing use only, not for direct human use.

2-(Allyloxy)benzaldehyde,98% stabilized with MEHQ|CS-W016117

Structure of 28752-82-1

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General Information

  • CAS No. 28752-82-1
  • Cat. No. CS-W016117
  • Purity 96% (stabilized with MEHQ)
  • MDL No. MFCD00014130
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₀O₂
  • Molecular Weight None
  • Synonym(s) TIMTEC-BB SBB007636
  • SMILES O=CC1=CC=CC=C1OCC=C

Description

2-(Allyloxy)benzaldehyde, stabilized with MEHQ, features a reactive allyl ether linkage and aldehyde functionality for use in transition-metal-catalyzed coupling reactions. The electron-rich aromatic ring enhances reactivity in Pd-mediated transformations, while the MEHQ stabilizer prevents peroxidation during storage. This bench-stable reagent integrates readily into synthetic sequences requiring selective functionalization.

Application

2-(Allyloxy)benzaldehyde, stabilized with MEHQ, serves as a versatile building block in synthetic organic chemistry, enabling efficient access to functionalized aromatic scaffolds. Its allyl ether functionality provides orthogonal reactivity for subsequent transformations, while the aldehyde group facilitates coupling reactions and heterocycle construction. The stabilization with MEHQ ensures shelf stability and reliable performance in bench-scale synthesis, making it well-suited for applications in medicinal chemistry and materials science.

Synthesis

  • Route1
    • null|null
      90-02-8
    • null|null
      106-95-6
    • ~99%
    • In-stock
      2-(Allyloxy)benzaldehyde,98% stabilized with MEHQ|CS-W016117
      28752-82-1

    References

    • Miege, Frederic; Meyer, Christophe; Cossy, Janine Angewandte Chemie - International Edition, 2011 , vol. 50, # 26 p. 5932 - 5937
  • Route2
    • In-stock
      2-Methylbenzyl alcohol|CS-0152955
      89-95-2
    • null|null
      106-95-6
    • ~95%
    • In-stock
      2-(Allyloxy)benzaldehyde,98% stabilized with MEHQ|CS-W016117
      28752-82-1

    References

    • Bashiardes, George; Safir, Imad; Mohamed, Achmet Said; Barbot, Francis; Laduranty, Joelle Organic Letters, 2003 , vol. 5, # 25 p. 4915 - 4918
  • Route3
    • null|null
      19244-42-9
    • ~93%
    • In-stock
      2-(Allyloxy)benzaldehyde,98% stabilized with MEHQ|CS-W016117
      28752-82-1

    References

    • Paul, Caroline E.; Rajagopalan, Aashrita; Lavandera, Ivan; Gotor-Fernandez, Vicente; Kroutil, Wolfgang; Gotor, Vicente Chemical Communications, 2012 , vol. 48, # 27 p. 3303 - 3305

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

Quality Control

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Computational Chemistry Data

  • TPSA   26.3
  • LogP   2.0639
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   4

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