Methyl N-phenylcarbamate

Name: Methyl N-phenylcarbamate
Brand: ChemScene
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CAS No. 2603-10-3
Cat. No. CS-0066443
Purity≥98%
MDL No.MFCD00027552

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 2603-10-3

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General Information

CAS No. 2603-10-3
Cat. No. CS-0066443
Purity ≥98%
MDL No. MFCD00027552
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₉NO₂
Molecular Weight 151.16
Synonym(s) N-Phenylcarbamic Acid Methyl Ester
SMILES O=C(NC1=CC=CC=C1)OC

Description

Methyl N-phenylcarbamate features a carbamate linkage flanked by a methyl ester and a phenyl group, delivering stability under standard bench conditions. This compound integrates readily into synthetic sequences requiring mild deprotection protocols, serving as a protected amine surrogate in peptide coupling and medicinal chemistry applications.

Application

Methyl N-phenylcarbamate serves as a stable, bench-ready carbamoylating agent for the selective introduction of urethane functionality. It facilitates efficient coupling with primary amines under mild conditions, enabling straightforward access to substituted ureas and carbamates. Its compatibility with diverse functional groups and ease of purification make it a practical choice in synthetic routes targeting pharmaceutical intermediates and heterocyclic scaffolds.

Synthesis

Route1
- 74497-02-2
- 616-38-6
- ~0%
- In-stock
  
  2603-10-3
- 121-69-7
- 100-61-8
References
- Li, Fang; Li, Wenbo; Li, Jing; Xue, Wei; Wang, Yanji; Zhao, Xinqiang Applied Catalysis A: General, 2014 , vol. 475, p. 355 - 362
Route2
- 79-22-1
- 622-37-7
- ~87%
- In-stock
  
  2603-10-3
References
- Yadav; Subba Reddy; Kiran Kumar Reddy New Journal of Chemistry, 2000 , vol. 24, # 8 p. 571 - 573
Route3
- 67-56-1
- 98-88-4
- ~89%
- In-stock
  
  2603-10-3
- 940-38-5
References
- Ishikawa, Hayato; Bondzic, Bojan P.; Hayashi, Yujiro European Journal of Organic Chemistry, 2011 , # 30 p. 6020 - 6031

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 38.33
LogP 1.8649
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Amine

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

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Methyl N-phenylcarbamate

CAS No. 2603-10-3

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